Solution-Processable Donor-Acceptor Copolymer Thin Films for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution.

Conjugated polymers (CPs) have been actively utilized as photocatalysts for hydrogen evolution due to their easy synthetic tunability to endow specific functionalities, including visible-light absorption, higher-lying LUMO energy for proton reduction, and sufficient photochemical stability. Enhancing interfacial surface and compatibility of hydrophobic CPs with hydrophilic water is the central focus to improve the hydrogen evolution rate (HER). Although a number of successful approaches have been developed in recent years, tedious chemical modifications or post-treatment of CPs make reproducibility of the materials difficult.

Formation of arrays of gallium nitride nanorods within mesoporous silica SBA-15.

We report the first formation of arrays of GaN nanorods inside the nanoscale channels of mesoporous silica SBA-15. GaCl3 dissolved in toluene was incorporated into the methyl group-functionalized SBA-15 powder. The pore surfaces functionalized with methyl groups should facilitate the impregnation with GaCl3.

Formation of titanium nitride nanoparticles within mesoporous silica SBA-15.

We report the first synthesis of titanium nitride (TiN) nanoparticles inside the nanoscale channels of mesoporous silica SBA-15. The TiN precursor, Ti(NMe(2))(4) in toluene, was incorporated into the methyl group-modified channels of the SBA-15 powder. The functionalization of pore surfaces with methyl groups generates hydrophobic surfaces that facilitate impregnation with Ti(NMe(2))(4) and minimizes reactions between the TiN precursor and the hydroxyl groups on the surface of SBA-15.