Coordination chemistry of tetrazolate-5-carboxylate with manganese(II): synthesis, structure and magnetism.

Six Mn(II) coordination compounds with tetrazolate-5-carboxylate (tzc), have been synthesized and characterized. They are of the formula [Mn2(tzc)2(H2O)2].4H2O (), Mn(tzc)(H2O)2 (), [Mn2(tzc)2(phen)2(H2O)2] (), [Mn(tzc)(2,2'-bpy)(H2O)2] (), [Mn(tzc)(4,4'-bpy)] () and [Mn2(tzc)2(H2O)2].