Electrolyte Design Enables Rechargeable LiFePO/Graphite Batteries from -80 °C to 80 °C.

Lithium iron phosphate (LFP)/graphite batteries have long dominated the energy storage battery market and are anticipated to become the dominant technology in the global power battery market. However, the poor fast-charging capability and low-temperature performance of LFP/graphite batteries seriously hinder their further spread. These limitations are strongly associated with the interfacial lithium (Li)-ion transport.

40 Years of Low-Temperature Electrolytes for Rechargeable Lithium Batteries.

Rechargeable lithium batteries are one of the most appropriate energy storage systems in our electrified society, as virtually all portable electronic devices and electric vehicles today rely on the chemical energy stored in them. However, sub-zero Celsius operation, especially below -20 °C, remains a huge challenge for lithium batteries and greatly limits their application in extreme environments. Slow Li diffusion and charge transfer kinetics have been identified as two main origins of the poor performance of RLBs under low-temperature conditions, both strongly associated with the liquid electrolyte that governs bulk and interfacial ion transport.

Taming Solvent-Solute Interaction Accelerates Interfacial Kinetics in Low-Temperature Lithium-Metal Batteries.

Lithium (Li)-metal batteries promise energy density beyond 400 Wh kg , while their practical operation at an extreme temperature below -30 °C suffers severe capacity deterioration. Such battery failure highly relates to the remarkably increased kinetic barrier of interfacial processes, including interfacial desolvation, ion transportation, and charge transfer. In this work, the interfacial kinetics in three prototypical electrolytes are quantitatively probed by three-electrode electrochemical techniques and molecular dynamics simulations.

The Crucial Role of Electrode Potential of a Working Anode in Dictating the Structural Evolution of Solid Electrolyte Interphase.

The performance of rechargeable lithium (Li) batteries is highly correlated with the structure of solid electrolyte interphase (SEI). The properties of a working anode are vital factors in determining the structure of SEI; however, the correspondingly poor understanding hinders the rational regulation of SEI. Herein, the electrode potential and anode material, two critical properties of an anode, in dictating the structural evolution of SEI were investigated theoretically and experimentally.

Multi-Conditional Constraint Generative Adversarial Network-Based MR Imaging from CT Scan Data.

Magnetic resonance (MR) imaging is an important computer-aided diagnosis technique with rich pathological information. The factor of physical and physiological constraint seriously affects the applicability of that technique. Thus, computed tomography (CT)-based radiotherapy is more popular on account of its imaging rapidity and environmental simplicity.

Modification of Nitrate Ion Enables Stable Solid Electrolyte Interphase in Lithium Metal Batteries.

The lifespan of high-energy-density lithium metal batteries (LMBs) is hindered by heterogeneous solid electrolyte interphase (SEI). The rational design of electrolytes is strongly considered to obtain uniform SEI in working batteries. Herein, a modification of nitrate ion (NO ) is proposed and validated to improve the homogeneity of the SEI in practical LMBs.

A Successive Conversion-Deintercalation Delithiation Mechanism for Practical Composite Lithium Anodes.

Lithium (Li) metal anodes are attractive for high-energy-density batteries. Dead Li is inevitably generated during the delithiation of deposited Li based on a conversion reaction, which severely depletes active Li and electrolyte and induces a short lifespan. In this contribution, a successive conversion-deintercalation (CTD) delithiation mechanism is proposed by manipulating the overpotential of the anode to restrain the generation of dead Li.

Reclaiming Inactive Lithium with a Triiodide/Iodide Redox Couple for Practical Lithium Metal Batteries.

High-energy-density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I /I ) redox couple initiated by stannic iodide (SnI ) is demonstrated to reclaim inactive Li. The reduction of I converts inactive Li into soluble LiI, which then diffuses to the cathode side.

Spine Computed Tomography to Magnetic Resonance Image Synthesis Using Generative Adversarial Networks : A Preliminary Study.

Objective: To generate synthetic spine magnetic resonance (MR) images from spine computed tomography (CT) using generative adversarial networks (GANs), as well as to determine the similarities between synthesized and real MR images.

Methods: GANs were trained to transform spine CT image slices into spine magnetic resonance T2 weighted (MRT2) axial image slices by combining adversarial loss and voxel-wise loss. Experiments were performed using 280 pairs of lumbar spine CT scans and MRT2 images.

Feasible Self-Calibration of Larger Field-of-View (FOV) Camera Sensors for the Advanced Driver-Assistance System (ADAS).

This paper proposes a self-calibration method that can be applied for multiple larger field-of-view (FOV) camera models on an advanced driver-assistance system (ADAS). Firstly, the proposed method performs a series of pre-processing steps such as edge detection, length thresholding, and edge grouping for the segregation of robust line candidates from the pool of initial distortion line segments. A novel straightness cost constraint with a cross-entropy loss was imposed on the selected line candidates, thereby exploiting that novel loss to optimize the lens-distortion parameters using the Levenberg-Marquardt (LM) optimization approach.

Deep CT to MR Synthesis Using Paired and Unpaired Data.

Magnetic resonance (MR) imaging plays a highly important role in radiotherapy treatment planning for the segmentation of tumor volumes and organs. However, the use of MR is limited, owing to its high cost and the increased use of metal implants for patients. This study is aimed towards patients who are contraindicated owing to claustrophobia and cardiac pacemakers, and many scenarios in which only computed tomography (CT) images are available, such as emergencies, situations lacking an MR scanner, and situations in which the cost of obtaining an MR scan is prohibitive.