Modeling Trihalomethane Increases Associated with Source Water Bromide Contributed by Coal-Fired Power Plants in the Monongahela River Basin.

Increases in source water bromide concentrations are challenging for drinking water utilities since bromide contributes to the formation of disinfection byproducts (DBPs) that have negative human-health effects. The present work evaluates the role of coal-fired power plant wet flue gas desulfurization (FGD)-associated bromide loads on in-stream bromide concentrations in the Monongahela River Basin in the water year (WY) 1998 (during a nationwide study) and over a five-year period from WYs 2013 through 2017. Under mean flow conditions in the lower Monongahela River for the WYs of interest, the median-estimated wet FGD bromide discharges are modeled to represent a significant fraction (27-57%) of observed bromide concentrations with the range representing the change in load conditions across WYs.

Disinfection byproduct regulatory compliance surrogates and bromide-associated risk.

Natural and anthropogenic factors can alter bromide concentrations in drinking water sources. Increasing source water bromide concentrations increases the formation and alters the speciation of disinfection byproducts (DBPs) formed during drinking water treatment. Brominated DBPs are more toxic than their chlorinated analogs, and thus have a greater impact on human health.