Publications by authors named "Chelsea E Stockwell"

Article Synopsis
  • The decline in vehicle emissions highlights the increasing role of Volatile Organic Compounds (VOCs) from Volatile Chemical Products (VCP), but their complex chemistry poses challenges for accurate modeling.
  • Researchers developed a new chemical mechanism called RACM2B-VCP to better represent VOC emissions from VCP sources, specifically in urban settings like Los Angeles.
  • Model evaluations show promising results, indicating that over 50% of anthropogenic VOC reactivity and ozone enhancement in the area is linked to VCP emissions, despite some remaining discrepancies in the model's overall VOC reactivity predictions.
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The COVID-19 stay-at-home orders issued in the United States caused significant reductions in traffic and economic activities. To understand the pandemic's perturbations on US emissions and impacts on urban air quality, we developed near-real-time bottom-up emission inventories based on publicly available energy and economic datasets, simulated the emission changes in a chemical transport model, and evaluated air quality impacts against various observations. The COVID-19 pandemic affected US emissions across broad-based energy and economic sectors and the impacts persisted to 2021.

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Volatile organic compounds (VOCs) emitted from biomass burning impact air quality and climate. Laboratory studies have shown that the variability in VOC speciation is largely driven by changes in combustion conditions and is only modestly impacted by fuel type. Here, we report that emissions of VOCs measured in ambient smoke emitted from western US wildfires can be parameterized by high- and low-temperature pyrolysis VOC profiles and are consistent with previous observations from laboratory simulated fires.

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Unit mass resolution mass spectral profiles of nonrefractory submicron aerosol were retrieved from undersampled atmospheric emission sources common to South Asia using a "mini" aerosol mass spectrometer. Emission sources including wood- and dung-fueled cookstoves, agricultural residue burning, garbage burning, engine exhaust, and coal-fired brick kilns were sampled during the 2015 Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE) campaign. High-resolution peak fitting estimates of the mass spectra were used to characterize ions found within each source profile and help identify mass spectral signatures unique to aerosol emissions from the investigated source types.

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Carbonaceous emissions from wildfires are a dynamic mixture of gases and particles that have important impacts on air quality and climate. Emissions that feed atmospheric models are estimated using burned area and fire radiative power (FRP) methods that rely on satellite products. These approaches show wide variability and have large uncertainties, and their accuracy is challenging to evaluate due to limited aircraft and ground measurements.

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Increasing air pollution in South Asia has serious consequences for air quality and human/ecosystem health within the region. South Asia, including India and Nepal, suffers from severe air pollution, including high concentrations of aerosols, as well as gaseous pollutants. One of the often-neglected sources contributing to the regional air pollution is garbage burning.

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Article Synopsis
  • * During the research, fluorine was found in PM2.5 emissions from coniferous trees and agricultural waste while being absent from other biomass types like peat and tire combustion.
  • * It is estimated that biomass burning contributes about 76 gigagrams of fluorine per year to the atmosphere, comparable to emissions from coal burning and showing potential for long-distance environmental transport.
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