Direct Evidence of Reversible Changes in Electrolyte and its Interplay with LiO Intermediate in Li-O Batteries.

Lithium-oxygen batteries show promising energy storage potential with high theoretical energy density; however, further investigation of chemical reactions is required. In this study, experimental Raman and theoretical analyzes are performed for a Li-O battery with LiClO/dimethyl sulfoxide (DMSO) electrolyte and carbon cathode to understand the role of intermediate species in the reactional mechanism of the cell using a high donor number solvent. Operando Raman results reveal reversible changes in the DMSO bands, in addition to the formation and decomposition of LiO.

LiOH Decomposition by NiO/ZrO in Li-Air Battery: Chemical Imaging with Operando Synchrotron Diffraction and Correlative Neutron/X-Ray Computed-Tomography Analysis.

Li-air batteries attract significant attention due to their highest theoretical energy density among all existing energy storage technologies. Currently, challenges related to extending lifetime and long-term stability limit their practical application. To overcome these issues and enhance the total capacity of Li-air batteries, this study introduces an innovative approach with NiO/ZrO catalysts.

Effect of Drying on the Fabrication of MgAl Layered Double Hydroxides.

This study aimed to evaluate the synthesis of MgAl/LDH from the drying process perspective, evaluating the influence of temperature (75-90 °C) and time (16-20 h) in the drying process. The synthesis was performed, maintaining a ratio of 2:1 of Mg/Al, and the drying was conducted according to a 2 experimental design: four axial points and three repetitions at the central point. The surface area and pore diameter ranged from 4.

Synchrotron XRD of Bromide Mediated Li-O Battery.

Li-O battery technology offers large theoretical energy density, considered a promising alternative energy storage technology for a variety of applications. One of the main advances made in recent years is the use of soluble catalysts, known as redox mediators (RM), decreasing the charge overpotential and improving cyclability. Despite its potential, much is still unknown regarding its dynamic, especially over higher loading electrodes, where mass transport may be an issue and the interplay with common impurities in the electrolyte, like residual water.

Degradation of Amaranth azo dye in water by heterogeneous photo-Fenton process using FeWO4 catalyst prepared by microwave irradiation.

FeWO4 particles were synthesized by a simple, rapid and facile microwave technique and their catalytic properties in heterogeneous photo-Fenton reaction were evaluated. This material was employed in the degradation of Amaranth azo dye. Individual and interactive effects of operational parameters such as pH, dye concentration and H2O2 dosage on the decolorization efficiency of Amaranth dye were evaluated by 2(3) central composite design.

Effects of Solvent Diols on the Synthesis of ZnFe₂O₄ Particles and Their Use as Heterogeneous Photo-Fenton Catalysts.

A solvothermal method was used to prepare zinc ferrite spinel oxide (ZnFe₂O₄) using ethylene glycol and 1,4 butanediol as solvent diols, and the influence of diols on the physical properties of ZnFe₂O₄ particles was investigated. The produced particles were characterized by X-ray powder diffraction (XRD), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption isotherms, and the catalytic activity for the organic pollutant decomposition by heterogeneous photo-Fenton reaction was investigated. Both solvents produced particles with cubic spinel structure.