In this study, geopolymer catalysts were synthesized by incorporating different TiO (0, 7, and 14 wt%) and FeO content (0, 7, 14, and 20 wt%) into porous metakaolin-based geopolymer granules. TiO- and FeO-immobilized geopolymer granules were applied for photocatalytic removals of imidacloprid under UV-C irradiation. The analysis of the surface morphology of the FeO catalyst revealed its larger surface area predominated with meso- and macro-pores thus providing a larger area for photocatalysis.
View Article and Find Full Text PDFAnaerobic pig wastewater treatment commonly generates high sulfide concentrations in the treated wastewater. This study aims to apply phototrophic green sulfur bacteria (PGB) to promote sulfide removal in lighting-anaerobic digestion (lighting-AD) treating pig wastewater. Initially, batch AD tests of pig wastewater with/without PGB addition were carried out under dark (D) and light (L) conditions.
View Article and Find Full Text PDFThis experimental research proposes an environment-friendly and low-cost porous geopolymer composite membrane (PGCM) to treat antibiotics in hospital wastewater. The proposed PGCM consisted of two layers: a porous support layer and a dense coating layer. The dense coating layer was synthesized by incorporating variable TiO content (0, 2, 6, and 10 wt%) into the geopolymer matrix.
View Article and Find Full Text PDFA pilot-scale of membrane bioreactor (MBR) had functioned without sludge withdrawal for six months, proposed to minimize antibiotic-resistant bacteria (ARB) dissemination from hospital wastewater. With this proposal, an aging sludge in MBR has concerned as preserved-severe multidrug-resistant microorganisms. Thus, this study aims to investigate resistance alteration of ARB in the aging-sludge compared to that in the wastewater.
View Article and Find Full Text PDFThe prevalence of antibiotic residues and antibiotic-resistant Escherichia coli (ARE) in closed (CSF) and open (OSF) pig farming systems was analysed. Results showed that a high level of E. coli populations, antibiotic contamination in supplied water, and additional antibiotics used, such as neomycin (NEO) or colistin (CLT), were observed in OSF.
View Article and Find Full Text PDFShallow windrow piles were applied as a low-cost option for biostabilisation of municipal solid wastes (MSW) prior to their utilization as refuse-derived fuel (RDF). A considerable amount of greenhouse gas (GHG) emissions can be emitted during the biostabilisation of MSW, especially when in operation under high moisture conditions such as there are in tropical Asia. This study investigated the emission of methane (CH) and nitrous oxide (NO) from shallow windrow piles - with heights of 0.
View Article and Find Full Text PDFTwo-stage MBR consisting of anaerobic and aerobic reactors was operated at total hydraulic retention time (HRT) of 48 h for the treatment of livestock wastewater containing antibiotics, i.e. amoxicillin (AMX), tiamulin (TIA), and chlortetracycline (CTC), under the (1st) absence and (2nd) presence of sludge recirculation between the reactors.
View Article and Find Full Text PDFIn this work, the removals of organic micro-pollutants (OMPs), i.e. DEP, DBP, 2,6-DTBP, BHT, and DEHP in sand, clay and iron powder mixed media of horizontal subsurface flow constructed wetland (HSSF) from landfill leachate were investigated over 3 years period.
View Article and Find Full Text PDFThe removal of organic micro-pollutants (OMPs) from landfill leachate in constructed wetland (CW) media having different material mixtures of sand (S), clay (C), and iron powder (Fe) was investigated using experimental column study. The use of S:C:Fe media consisting of 60:30:10% (w/w) and cattail as vegetation was found optimum for the removals of 2,6-DTBP, BHT, DEP, DBP, and DEHP at 67.5-75.
View Article and Find Full Text PDFRemovals of 10 pharmaceutical compounds by microbial sludge in membrane bioreactors (MBR) operated under infinite and limited solid retention time (SRT) were investigated. High removal (>80%) of DCF, TMP, NPX, IBP, and TCS were achieved but CBZ removals were low (<20%). The residual pharmaceutical compounds leftover from the biodegradation in different sludge particle size fractions was quantified through physical separation and filtration in series.
View Article and Find Full Text PDFThe harbor sediment containing high concentration of heavy metals may pose serious impacts on the marine ecosystem and environmental quality. The bioleaching process has been considered as an environmentally friendly and cost-effective alternative for removing heavy metals from contaminated sediments. In this study, a series of experiments were performed to investigate the feasibility of bioleaching process for removing heavy metals from the contaminated harbor sediments.
View Article and Find Full Text PDFTwo landfill test cells, with and without gas vents, were used to investigate the effectiveness of passive aeration, through basal leachate pipes, in mitigating methane emissions from municipal solid waste disposal in the tropical climate of Thailand. Surface methane emission rate, as well as methane content in the landfill gas, were determined for a period of three years. The results indicate that the average methane emission rate from the test cell with passive gas vents (42.
View Article and Find Full Text PDFGenotoxicity model is developed to assess the individual subacute toxicity of benzene, toluene, ethylbenzene, and xylene (BTEX) at very low levels as in a landfill gas. Golden Pothos (Epipremnum aureum), a higher plant, was tested under variation of benzene 54-5656 ng/L, toluene 10-4362 ng/L, ethylbenzene 28-4997 ng/L, xylene 53-4845 ng/L, for 96 h. DNA fragmentation in plant leaves were investigated via comet assay.
View Article and Find Full Text PDFThe role of autotrophic nitrification on the biodegradation of toxic organic micro-pollutants presented in landfill leachate was assessed. A two-stage MBR system consisting of an inclined tube incorporated anoxic reactor followed by aerobic submerged membrane reactor was operated under long sludge age condition in which nitrifying bacteria could be enriched. During the reactor operation, organic removal efficiencies were more than 90% whereas phenolic compounds including bisphenol A (BPA) and 4-methyl-2,6-di-tert-butylphenol (BHT) were removed by 65 and 70% mainly through biodegradation in the aerobic reactor even at high feed concentrations of 1000μg/L for both compounds.
View Article and Find Full Text PDFThe kinetic of phenolic and phthalic acid esters (PAEs) biodegradation in membrane bioreactor (MBR) treating municipal landfill leachate was investigated. Laboratory-scale MBR was fed with mixture of fresh and stabilized landfill leachate containing carbon to nitrogen (C/N) ratio of 10, 6, 3 and operated under different solid retention time (SRT) of 90, 15 and 5 d. Batch experiments using MBR sludge obtained from each steady-state operating condition revealed highest biodegradation rate constant (k) of 0.
View Article and Find Full Text PDFRiver water samples were taken from 32 locations around the basin of Chaophraya River and its four major tributaries in Thailand to investigate resistance ratios of Escherichia coli isolates to eight antibiotic agents of amoxicillin, sulfamethoxazole/trimethoprim, tetracycline, doxytetracycline, ciprofloxacin, levofloxacin, norfloxacin and ofloxacin. Principal component analysis was performed to characterize resistance patterns of the samples. Relevancy of the obtained principal components with urban land use and fecal contamination of the river were examined.
View Article and Find Full Text PDFOnly 3.4% of total water use in the Bangkok Metropolitan area is reused treated sewage. This study anticipates that further treated-sewage reuse in industrial sectors, commercial buildings and public parks, in addition to present in-plant and street cleaning purposes, would increase total water reuse to about 10%.
View Article and Find Full Text PDFThis research investigated the membrane fouling and micro-pollutant removals in treatment of municipal landfill leachate at various pH levels (i.e. 5.
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