Effect of electrostatic interactions on rejection of capsular and spherical particles from porous membranes: theory and experiment.

Hypotheses: Particle rejection from porous membranes will increase when particle and membrane carry like charges. The influence of charge on particle rejection can be modeled by first solving the Poisson-Boltzmann equation for the electrostatic particle-pore wall interaction energy, enabling one to predict the cross sectional particle concentration in a pore. Rejection coefficients can then be predicted by combining the Boltzmann factor with a hydrodynamic lag coefficient.

Relative insignificance of virus inactivation during aluminum electrocoagulation of saline waters.

Combined removal and inactivation of the MS2 bacteriophage from model saline (0-100 mM NaCl) waters by electrochemical treatment using a sacrificial aluminum anode was evaluated. Both chemical and electrodissolution contributed to coagulant dosing since measured aluminum concentrations were statistically higher than purely electrochemical predictions using Faraday's law. Electrocoagulation generated only small amounts of free chlorine in situ but effectively destabilized viruses and incorporated them into Al(OH)3(s) flocs during electrolysis.

Sweep flocculation and adsorption of viruses on aluminum flocs during electrochemical treatment prior to surface water microfiltration.

Bench-scale experiments were performed to evaluate virus control by an integrated electrochemical-microfiltration (MF) process from turbid (15 NTU) surface water containing moderate amounts of dissolved organic carbon (DOC, 5 mg C/L) and calcium hardness (50 mg/L as CaCO3). Higher reductions in MS2 bacteriophage concentrations were obtained by aluminum electrocoagulation and electroflotation compared with conventional aluminum sulfate coagulation. This was attributed to electrophoretic migration of viruses, which increased their concentrations in the microenvironment of the sacrificial anode where coagulant precursors are dissolved leading to better destabilization during electrolysis.

Mechanisms of virus control during iron electrocoagulation--microfiltration of surface water.

Results from a laboratory-scale study evaluating virus control by a hybrid iron electrocoagulation - microfiltration process revealed only 1.0-1.5 log MS2 bacteriophage reduction even at relatively high iron dosages (≈ 13 mg/L as Fe) for natural surface water containing moderate natural organic matter (NOM) concentrations (4.