In this study, lead removal from aqueous solutions using biochar derived from olive mill solid and liquid wastes has been investigated by applying batch experiments and geochemical modelling. The batch adsorption experiments included the assessment of several key parameters such as the contact time (kinetic), initial concentration (isotherm), pH, adsorbent dose, and the presence of competitive cations, whilst the geochemical modelling focused on the involved adsorption mechanisms using the PHREEQC code. The kinetic studies showed that lead adsorption is a relatively fast process, where intraparticle diffusion is the rate-limiting step.
View Article and Find Full Text PDFHydrothermal carbonization (HTC) is considered as a promising technique for wastes conversion into carbon rich materials for various energetic, environmental and agricultural applications. In this work, the HTC of olive mill wastewater (OMWW) was investigated at different temperatures (180-220 °C) and both, the solid (i.e.
View Article and Find Full Text PDFAssessments of the environmental impact of C-14 disposal often assume that C-14 is converted into gases that are able to migrate to the surface, where they pose a radiological risk. However, uncertainties, associated with the long-term release of C-14 from graphite and the evolution in the post-closure environment of a geological disposal facility (GDF), exist. In this paper, an integrated modelling framework has been developed to investigate these uncertainties.
View Article and Find Full Text PDFOne design concept for the long-term management of the UK's intermediate level radioactive wastes (ILW) is disposal to a cementitious geological disposal facility (GDF). Under the alkaline (10.0
The ability to apply an ecosystem approach to the Strymonas River catchment was investigated using the MIKE 11 modeling system for the simulation of surface water. The Strymonas River catchment is shared mainly between Bulgaria and Greece. The river feeds the artificial Lake Kerkini, a significant wetland ecosystem, and further downstream it outflows to the Gulf of Strymonikos, whose estuary ecosystem is very important for fisheries, biodiversity and tourism.
View Article and Find Full Text PDF