Amorphization engineering of Ni-cysteine coordination composition for urea electro-oxidation at large current density.

Unavoidable oxygen evolution reaction (OER) and the relatively high potential to form real active sites of Ni species severely decrease the efficiency of urea-assisted hydrogen generation facility. Herein, amorphization Ni-cysteine coordination (aNi-cys) is constructed as efficient urea electro-oxidation reaction (UOR) catalyst with highly capable of suppressing competitive OER and promoting the Ni to Ni in-situ electrochemical configuration through deliberately regulating the Ni/l-cysteine coordination environment. The abundant ligand atoms (N, S, and O) of l-cysteine considerably tuned the Ni electronic structure to the most suitable state while the amorphization thin lamellas increased the exposed active sites and befitting for the access of electrolyte to electrode surface, resulting improved UOR activity with a large peak current density of 263 mA cm, far exceeding crystalline Ni-cysteine coordination (cNi-cys) and long-term stability for 50 h working.

Radar Target Radar Cross-Section Measurement Based on Enhanced Imaging and Scattering Center Extraction.

Accurate measurement of a Radar Cross-Section (RCS) is a critical technical challenge in assessing the stealth performance and scattering characteristics of radar targets. Traditional RCS measurement methods are limited by high costs, sensitivity to environmental conditions, and difficulties in distinguishing local scattering features of targets. To address these challenges, this paper proposes a novel RCS measurement method based on enhanced imaging and scattering center extraction.

Calibration-free and ready-to-use wearable electroanalytical reporting system (r-WEAR) for long-term remote monitoring of electrolytes markers.

A major bottleneck in the development of wearable ion-selective sensors is the inherent conditioning and calibration procedures at the user's end due to the signal's instability and non-uniformity. To address this challenge, we developed a strategy that integrates three interdependent materials and device engineering approaches to realize a Ready-to-use Wearable ElectroAnalytical Reporting system (r-WEAR) for reliable electrolytes monitoring. The strategy collectively utilized (1) finely-configured diffusion-limiting polymers to stabilize the electromotive force in the electrodes, (2) a uniform electrical induction in electrochemical cells to normalize the open-circuit potential (OCP), and (3) an electrical shunt to maintain the OCP across the entire sensor in the r-WEAR.

Acidic Leucine-Rich Nuclear Protein Phosphatase 32B Promotes Prostate Adenocarcinoma Cell Progression by Regulating Apoptosis and Epithelial-Mesenchymal Transition.

Objective: This work aimed to investigate the expression of acidic leucine-rich nuclear protein phosphatase 32B (ANP32B) in prostate adenocarcinoma (PRAD) and evaluate the effect of ANP32B on the proliferation of prostate adenocarcinoma cells.

Methods: We evaluated the expression of ANP32B in PRAD tissues and cells compared to the controls obtained from The Cancer Genome Atlas (TCGA). siRNA targeting ANP32B was transfected into DU145 cells to knockdown the ANP32B expression and plasmids carrying ANP32B coding region were used to overexpress ANP32B in PC3 cells.

Comparative Study of the Effects of Dietary-Free and -Bound Nε-Carboxymethyllysine on Gut Microbiota and Intestinal Barrier.

Nε-carboxymethyllysine (CML) is produced by a nonenzymatic reaction between reducing sugar and ε-amino group of lysine in food and exists as free and bound forms with varying digestibility and absorption properties , causing diverse interactions with gut microbiota. The effects of different forms of dietary CML on the gut microbiota and intestinal barrier of mice were explored. Mice were exposed to free and bound CML for 12 weeks, and colonic morphology, gut microbiota, fecal short-chain fatty acids (SCFAs), intestinal barrier, and receptor for AGE (RAGE) signaling cascades were measured.

Environmental behaviors and toxic mechanisms of engineered nanomaterials in soil.

Engineered nanomaterials (ENMs) are inevitably released into the environment with the exponential application of nanotechnology. Parts of ENMs eventually accumulate in the soil environment leading to potential adverse effects on soil ecology, crop production, and human health. Therefore, the safety application of ENMs on soil has been widely discussed in recent years.

Tracing COVID-19 drugs in the environment: Are we focusing on the right environmental compartment?

The Coronavirus Disease 2019 (COVID-19) pandemic led to over 770 million confirmed cases, straining public healthcare systems and necessitating extensive and prolonged use of synthetic chemical drugs around the globe for medical treatment and symptom relief. Concerns have arisen regarding the massive release of active pharmaceutical ingredients (APIs) and their metabolites into the environment, particularly through domestic sewage. While discussions surrounding this issue have primarily centered on their discharge into aquatic environments, particularly through treated effluent from municipal wastewater treatment plants (WWTPs), one often overlooked aspect is the terrestrial environment as a significant receptor of pharmaceutical-laden waste.

Mitigating Jahn-Teller Effect in Layered Cathode Material Via Interstitial Doping for High-Performance Sodium-Ion Batteries.

Layered transition metal oxides are promising cathode materials for sodium-ion batteries due to their high energy density and appropriate operating potential. However, the poor structural stability is a major drawback to their widespread application. To address this issue, B is successfully introduced into the tetrahedral site of Na Fe Mn O , demonstrating the effectiveness of small-radius ion doping in improving electrochemical performance.

Comparative review on microbial electrochemical technologies for resource recovery from wastewater towards circular economy and carbon neutrality.

Newly arising concepts such as the circular economy and carbon neutrality motivate resource recovery from wastewater. This paper reviews and discusses state-of-the-art microbial electrochemical technologies (METs), specifically microbial fuel cells (MFCs), microbial electrolysis cells (MECs) and microbial recycling cells (MRCs), which enable energy generation and nutrient recovery from wastewater. Mechanisms, key factors, applications, and limitations are compared and discussed.

Granulomatous Inflammation of Greater Omentum Caused by a Migrating Fishbone.

Fishbone is the most common ingested gastrointestinal foreign matter and is less than 1% perforate. However, a fishbone penetrating the gastrointestinal tract and causing granulomatous inflammation of the greater omentum with local suppuration is not common. Because of the nonspecific clinical symptoms, gastrointestinal perforation may be manifested only as dull abdominal pain, which is often ignored and timely clinical treatment may be delayed.

Municipal solid waste, an overlooked route of transmission for the severe acute respiratory syndrome coronavirus 2: a review.

Municipal solid waste could potentially transmit human pathogens during the collection, transport, handling, and disposal of waste. Workers and residents living in the vicinity of municipal solid waste collection or disposal sites are particularly susceptible, especially unprotected workers and waste pickers. Recent evidence suggests that municipal solid waste-mediated transmission can spread the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) to humans.

A "two-step" assay based on electro-activation for rapid determination of methylglyoxal in honey and beer.

Methylglyoxal (MGO), a dicarbonyl compound in living organism, food and environment, has been associated with disease diagnosis and human health. The current electrochemical detection methods rely on the use of advanced materials. In this work, a non-advanced materials "two-step" assay including electrode electro-activation and MGO detection was developed.

MiR-22-3p Suppresses Cell Migration and Invasion by Targeting PLAGL2 in Breast Cancer.

Objective: To investigate the expression of miR-22-3p in breast cancer and the mechanism of targeting PLAGL2 to inhibit the invasion and migration in human breast cancer.

Study Design: An experimental study.

Place And Duration Of Study: Department of Oncology and Department of General Surgery, The People's Hospital of China Three Gorges University, China, from March 2019 to December 2020.

Twin boundary defect engineering improves lithium-ion diffusion for fast-charging spinel cathode materials.

Defect engineering on electrode materials is considered an effective approach to improve the electrochemical performance of batteries since the presence of a variety of defects with different dimensions may promote ion diffusion and provide extra storage sites. However, manipulating defects and obtaining an in-depth understanding of their role in electrode materials remain challenging. Here, we deliberately introduce a considerable number of twin boundaries into spinel cathodes by adjusting the synthesis conditions.

[Research progress of intramedullary lengthening nail technology].

Objective: To review the research progress of intramedullary lengthening nail technology.

Methods: The foreign literature on the development history, types, advantages and disadvantages, indications and contraindications, complications, and effectiveness of intramedullary lengthening nail were reviewed and analyzed.

Results: The intramedullary lengthening nail system mainly includes mechanical type, electric motor drive type, and magnetic drive type.

Enhancing the Electrochemical Performance and Structural Stability of Ni-Rich Layered Cathode Materials via Dual-Site Doping.

Ni-rich layered cathode materials are considered as promising electrode materials for lithium ion batteries due to their high energy density and low cost. However, the low rate performance and poor electrochemical stability hinder the large-scale application of Ni-rich layered cathodes. In this work, both the rate performance and the structural stability of the Ni-rich layered cathode LiNiCoMnO are significantly improved via the dual-site doping of Nb on both lithium and transition-metal sites, as revealed by neutron diffraction results.

General Synthesis of Amorphous PdM (M = Cu, Fe, Co, Ni) Alloy Nanowires for Boosting HCOOH Dehydrogenation.

Noble metal-based nanomaterials with amorphous structures are promising candidates for developing efficient electrocatalysts. However, their synthesis remains a significant challenge, especially under mild conditions. In this paper, we report a general strategy for preparing amorphous PdM nanowires (a-PdM NWs, M = Fe, Co, Ni, and Cu) at low temperatures by exploiting glassy non-noble metal (M) nuclei generated by special ligand adsorption as the amorphization dictator.

Ethylene and salicylic acid synergistically accelerate leaf senescence in Arabidopsis.

The phytohormones ethylene and salicylic acid (SA) have long been known to promote senescence, but their interplay during this process remains elusive. Here we report the synergistic effects of ethylene and SA on promoting leaf senescence in Arabidopsis. EIN3, a key transcription factor of ethylene signaling, physically interacted with the core SA signaling regulator NPR1 in senescing leaves.

The transcription factor ZmNAC126 accelerates leaf senescence downstream of the ethylene signalling pathway in maize.

Leaf senescence is an integral part of plant development, during which, nutrients are remobilized from senescent leaves to fast-growing organs. The initiation and progression dynamics of leaf senescence is therefore vital not only to the maximal accumulation of assimilates but also to the efficient remobilization of nutrients. Senescence is a finely tuned process that involves the action of a large number of transcription factors (TFs).

Prognostic role of pretreatment lactate dehydrogenase in patients with metastatic renal cell carcinoma: A systematic review and meta-analysis.

Background: To date, there remain uncertainties over the prognostic role of serum lactate dehydrogenase (LDH) in patients with metastatic renal cell carcinoma (mRCC). A systematic review and meta-analysis was performed.

Materials And Methods: Eligible studies were retrieved from PubMed, Embase, Cochrane Library and Web of Science databases up to October 2019.

A new water treatment technology for degradation of B[a]A by hydrodynamic cavitation and chlorine dioxide oxidation.

Managing environmental contamination with Benz[a]anthracene (B[a]A) is essential due to its carcinogenic, teratogenic and mutagenic effects on humans and the environment. At present, the mainly B[a]A degradation methods used are photodegradation, bioremediation and traditional advanced oxidation, although they all have disadvantages. In this study, B[a]A was degraded by hydrodynamic cavitation (HC), chlorine dioxide (ClO), or an innovative combination of the two methods.

Etching-Assisted Route to Heterophase Au Nanowires with Multiple Types of Active Surface Sites for Silane Oxidation.

The construction of multiple types of active sites on the surface of a metallic catalyst can markedly enhance its catalytic activity toward specific reactions. Here, we show that heterophase gold nanowires (Au NWs) with multiple types of active surface sites can be synthesized using an etching-assisted process, yielding the highest reported turnover frequency (TOF) for Au catalysts toward the silane oxidation reaction by far. We use synchrotron powder X-ray diffraction (PXRD) and aberration-corrected (scanning) transmission electron microscopy (TEM) to show that the Au NWs contain heterophase structures, planar defects, and surface steps.

H-Induced coalescence of Pt nanoparticles for the preparation of ultrathin Pt nanowires with high-density planar defects.

Construction of planar defects within a metallic catalyst can significantly improve its catalytic performance. However, it remains a huge challenge to introduce planar defects during the synthesis of metallic catalysts. In this work, we have reported an effective approach for the preparation of Pt nanowires with high-density planar defects.