A Fe-catalyzed hydrocyclization reaction of unactivated alkenes was developed, utilizing PhSiH as the hydrogen source, yielding 2,3-dihydroquinazolinone (DHQZ) derivatives in moderate to good yields. Notably, when the substrate was switched to -cyano--(2-(prop-1-en-2-yl)phenyl)benzamides, the reaction yielded only the unreduced products. Mechanistic studies revealed that the intramolecular addition of the in situ formed radical to the unactivated alkene results in the formation of the fused ring.
View Article and Find Full Text PDFShanghai Kou Qiang Yi Xue
October 2024
Purpose: To investigate the expression of ubiquitin specific protease 20 (USP20) in oral squamous cell carcinoma (OSCC) and its correlation with clinicopathological parameters.
Methods: OSCC samples and paired paracancerous samples were screened from the TCGA database for differential expression analysis and paired differential analysis. Immunohistochemical staining was used to detect the expression level of USP20 in OSCC tissue, paracancerous tissues and normal tissues.
Background: The growth and yield of pepper, a typical temperature-loving vegetable, are limited by low-temperature environments. Using low-temperature sensitive 'Hangjiao No. 4' (Capsicum annuum L.
View Article and Find Full Text PDFNested subset pattern (nestedness) is an important part of the theoretical framework of island biogeography and community ecology. However, most previous studies often used nestedness metrics or randomization algorithms that are vulnerable to type I error. In this study, we investigated the nestedness of lizard assemblages on 37 islands in the Zhoushan Archipelago, China.
View Article and Find Full Text PDFCadmium (Cd) contamination is a serious global concern that warrants constant attention. Therefore, a hydroponic study was conducted to evaluate the effect of different concentrations (0, 1, 2.5, 5, 10, 15 mg/l) of zinc oxide nanoparticles (ZnONPs) on the Cd content in lettuce () under Cd stress conditions.
View Article and Find Full Text PDFThe ZIP protein (ZRT, the IRT-like protein) is an important metal transporter that transports Zn, Fe, and other divalent metal ions in plants. In this study, we identified 20 ZIP genes in lettuce (Lactuca sativa L.).
View Article and Find Full Text PDFGravel and sand mulching is an indigenous technology that has been used for increasing soil temperature and improving crop yield and water use efficiency for at least 300 years in northwestern China. However, long-term application of inorganic fertilizer with gravel and sand mulch could decrease the soil organic carbon content, and how to improve soil fertility under gravel and sand mulching remains largely unknown. Thus, we evaluated the effects of the application of inorganic (chemical) and organic (manure) fertilizers on the distribution of soil aggregates and their associated organic carbon in a field mulched with gravel and sand.
View Article and Find Full Text PDFTo avoid the negative impact of excessive fertilization on vegetable production, a decreased fertilization experiment was conducted in a multi-layer covered plastic greenhouse in 2017 to 2018. Treatments included no fertilizer (CK), traditional fertilization (TF), slow-release fertilizers (SRF), and decreased fertilization with slow-release fertilizers (DSRF). Results showed that the SRF and DSRF increased leaf length (13% and 8.
View Article and Find Full Text PDFAs a typical thermophilous vegetable, the growth and yield of peppers are easily limited by chilling conditions. Zeaxanthin, a crucial carotenoid, positively regulates plant abiotic stress responses. Therefore, this study investigated the regulatory mechanisms of zeaxanthin-induced chilling tolerance in peppers.
View Article and Find Full Text PDFOptimal plant growth in many species is achieved when the two major forms of N are supplied at a particular ratio. In this pot experiment, the effects of five different ammonium:nitrate ratios (ANRs) (0:100, 12.5:87.
View Article and Find Full Text PDFOptimal plant growth in many species is achieved when the two major forms of N are supplied at a particular ratio. In this pot experiment, the effects of five different ammonium:nitrate ratios (ANRs) (0:100, 12.5:87.
View Article and Find Full Text PDFCarotenoids are considered to be crucial elements in many fields and, furthermore, the significant factor in pepper leaves under low light and chilling temperature. However, little literature focused on the method to determinate and extract the contents of carotenoid compositions in pepper leaves. Therefore, a time-saving and highly sensitive reversed-phase high-performance liquid chromatography method for separation and quantification of 10 carotenoids was developed, and an optimized technological process for carotenoid composition extraction in pepper leaves was established for the first time.
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