Two Facile Aniline-Based Hypercrosslinked Polymer Adsorbents for Highly Efficient Iodine Capture and Removal.

Effective capture and safe disposal of radioactive iodine (I or I) during nuclear power generation processes have always been a worldwide environmental concern. Low-cost and high-efficiency iodine removal materials are urgently needed. In this study, we synthesized two aniline-based hypercrosslinked polymers (AHCPs), AHCP-1 and AHCP-2, for iodine capture in both aqueous and gaseous phases.

Graphene quantum dots: efficient mechanosynthesis, white-light and broad linear excitation-dependent photoluminescence and growth inhibition of bladder cancer cells.

Heteroatom-doped graphene quantum dots (GQDs) have attracted considerable attention due to their potential applications as luminescent materials and in biology. In this work, we developed a solvent-free gram-scale mechanochemical method for the preparation of nitrogen-doped graphene quantum dots (N-GQDs) with the highest solubility (31 mg mL) in water reported to date. Commercial graphite was sheared and cut through grinding with solid melamine and then ground with solid KOH to get sub-5 nm-sized, 1-3-layered N-GQDs.

NaCl as a solid solvent to assist the mechanochemical synthesis and post-synthesis of hierarchical porous MOFs with high I vapour uptake.

The use of salts as grinding media to assist the mechanosynthesis, and the following one-pot mechanochemical post-synthesis, of hierarchically porous MOFs was carried out efficiently by ball milling. NaCl or KCl were used as a solid solvent to initially pre-grind with 1,3,5-benzenetricarboxylic acid (H3BTC) and copper acetate monhydrate, respectively, for 1 minute, then both mixtures were combined together for a further 20 minutes of grinding, and the resultant mixture was finally washed with ethanol and water to obtain the hierarchically micro-, meso- and macroporous HKUST-1 with a high yield. Moreover, the post-synthesis of these as-obtained hierarchically porous HKUST-1 was easily performed via grinding triethylenediamine (TED) with the above unwashed crude-products for 20 minutes.

Surfactant-free scalable synthesis of hierarchically spherical Co3O4 superstructures and their enhanced lithium-ion storage performances.

Unique hierarchically porous spherical Co(3)O(4) superstructures were synthesized via a surfactant-free hydrothermal process followed by a calcination treatment, in which the concentration of reactant cobalt (II) nitrate hexahydrate is a key factor affecting the morphology of products. X-ray powder diffraction, electron microscopies (TEM and SEM), and thermogravimetric analysis were employed to investigate the formation of Co(3)O(4) spherical superstructures. Our results suggest that they formed from numerous cubic Co(3)O(4) nanocrystals via an oriented attachment mechanism.

Cobalt-doping-induced synthesis of ceria nanodisks and their significantly enhanced catalytic activity.

High-quality cobalt-doped ceria nanostructures with triangular column, triangular slab, and disklike shapes are synthesized by tuning the doping amount of cobalt nitrate in a facile hydrothermal reaction. The cobalt-doped ceria nanodisks display significantly enhanced catalytic activity in CO oxidation due to exposed highly active crystal planes and the presence of numerous surface defects.