Technologies that enable surface modification are in high demand and are critical for the implementation of new functional materials and devices. Here, we describe the first modification of a carbon surface (in this case carbon fiber) using the sulfur-fluoride exchange (SuFEx) reaction. The parent sulfur (VI) fluoride moiety can be installed directly to the surface via electrochemical deposition of the fluorosulfate phenyldiazonium tetrafluoroborate salt, or by 'SuFExing' a phenol on the carbon surface followed by treatment of the material with SO F ; similar to a 'graft to' or 'graft from' functionalization approach.
View Article and Find Full Text PDFTesting methodologies to accurately quantify interfacial shear strength (IFSS) are essential in order to understand fiber-matrix adhesion. While testing methods at a microscale (single filament fragmentation test-SFFT) and macroscale (Short Beam Shear-SBS) are wide spread, each have their own shortcomings. The Iosipescu (V-notch) tow test offers a mesoscale bridge between the microscale and macroscale whilst providing simple, accurate results with minimal time investment.
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