Mater Sci Eng A Struct Mater
November 2016
The effects of micro-additions of boron and zirconium on grain-boundary (GB) structure and strength in polycrystalline γ(f.c.c.
View Article and Find Full Text PDFWhat determines the morphology of a decomposing alloy? Besides the well-established effect of the nucleation barrier, we demonstrate that, in a concentrated multicomponent Ni(Al,Cr) alloy, the details of the diffusion mechanism strongly affect the kinetic pathway of precipitation. Our argument is based on the combined use of atomic-scale observations, using three-dimensional atom-probe tomography (3D APT), lattice kinetic Monte Carlo simulations and the theory of diffusion. By an optimized choice of thermodynamic and kinetic parameters, we first reproduce the 3D APT observations, in particular the early-stage transient occurrence of coagulated precipitates.
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