Humic-like components in dissolved organic matter inhibit cadmium sequestration by sediment.

China's lakes are plagued by cadmium (Cd) pollution. Dissolved organic matter (DOM) significantly regulates Cd(II) transport properties at the sediment-water interface. Understanding the effects of different DOM components on the transportation properties of Cd(II) at the sediment-water interface is essential.

Isolation and Identification of Highly Sb-Resistant Rhodotorula glutinis Strain J5 and its Mechanism of Resistance to Sb(III).

Sb-resistant strains can detoxify antimony through metabolic mechanisms such as oxidation and affect the migration, transformation, and ultimate fate of antimony in the environment. In this study, a strain of Sb-resistant fungi, Rhodotorula glutinis sp. Strain J5, was isolated from Xikuangshan mine and its growth characteristics, gene expression differences, and functional annotation under Sb(III) stress were further investigated to reveal the mechanism of resistance to Sb(III).

Mechanisms of cadmium release from manganese-rich sediments driven by exogenous DOM and the role of microorganisms.

Dissolved organic matter (DOM) is a crucial component of natural sediments that alters Cd sequestration. Nevertheless, how different types of DOM fuel Cd mobilization in Mn-rich sediments has not been elucidated. In the present study, four typical DOM, fluvic acid (FA), bovine serum albumin (BSA), sodium alginate (SA), and sodium dodecyl benzene sulfonate (SDBS), were used to amend Cd-contaminated sediment to study their effects on Cd/Mn biotransformation and microbial community response.

Manganese oxides mediated dissolve organic matter compositional changes in lake sediment and cadmium binding characteristics.

In sediment environments, manganese (Mn) minerals have high dissolved organic matter (DOM) affinities, and could regulate the changes of DOM constituents and reactivity by fractionation. However, the effects of DOM fractionation by Mn minerals on the contaminant behaviors remain unclear. Herein, the transformations of mineral phases, DOM properties, and Cd(II) binding characteristics to sediment DOM before and after adsorption by four Mn oxides (δ-MnO, β-MnO, γ-MnOOH, and MnO) were investigated using multi-spectroscopic tools.

Binding of Cd(II) to birnessite and fulvic acid organo-mineral composites and controls on Cd(II) availability.

Manganese oxide minerals (MnOs) are major controls on cadmium (Cd) mobility and fate in the environment. However, MnOs are commonly coated with natural organic matter (OM), and the role of this coating in the retention and availability of harmful metals remains unclear. Herein, organo-mineral composites were synthesized using birnessite (BS) and fulvic acid (FA), during coprecipitation with BS and adsorption to preformed BS with two organic carbon (OC) loadings.

[Characteristics and Sources of DOM in Lake Sediments Under Different Inundation Environments].

The characteristics and sources of DOM in sediments are significantly affected by fluctuations in lake water levels. However, the impact of spatial differences on water levels remain unclear. Here, 36 sediment samples were collected from the flood passage and coastal beach of East Dongting Lake.

How do drying-wetting cycles influence availability of heavy metals in sediment? A perspective from DOM molecular composition.

Investigating the influence mechanism of drying-wetting cycles on the availability and mobility of heavy metals in sediment from the perspective of the molecular composition of dissolved organic matter (DOM) may gain a new understanding, but little current information exists. Here, we used spectral technologies, high-resolution mass spectrometry, and elemental stoichiometry method to trace the change rules of the molecular composition of DOM in the riparian sediment of the river. Results showed that the drying-wetting cycles could benefit the degradation of labile fractions (e.

Cadmium immobilization in lake sediment using different crystallographic manganese oxides: Performance and mechanism.

Cd pollution in sediments poses severe threats to environmental safety and human health. Mn oxides have potential merit for the remediation of Cd pollution in sediment but have not received enough attention. Although Mn oxides have proven effective as adsorbents for removing heavy metals from water/wastewater, the performance and the underlying mechanism of Cd immobilization in sediments by Mn oxides remain unclear.

Effects of pyrolysis temperature on proton and cadmium binding properties onto biochar-derived dissolved organic matter: Roles of fluorophore and chromophore.

Understanding the environmental behavior of biochar-derived dissolved organic matter (BDOM) is crucial for promoting the extensive utilization of biochar and meeting the carbon neutrality targets. However, limited studies focused on the binding mechanism of protons and Cd with DOM released from biochar produced at different pyrolysis temperatures. By combining excitation-emission matrix spectroscopy and parallel factor analysis, we found that the humic-like fluorophores in BDOM had higher aromaticity, molecular weight, and contents of carboxylic and phenolic groups relative to the protein-like fluorophores.

Fe oxides and fulvic acids together promoted the migration of Cd(II) to the root surface of Phragmites australis.

Dissolved organic matter (DOM) or iron/manganese (hydro)oxides were important factors in the migration of Cd in sediments of wetlands. DOM and Fe oxides simultaneously affect the longitudinal and transverse migration of Cd in wetlands sediments of plants was still unclear. In this study, a 14-day rhizobox experiment was conducted and the result showed that the rhizosphere effect of Cd migration was only limited to the upper layer of sediments (- 2 to - 4 cm).

[Promotion and Mechanisms of DOM on Copper Adsorption by Suspended Sediment Particles].

The adsorption of heavy metals by suspended sediment particles is a key process in the migration of heavy metals in lakes and is affected by various environmental conditions. To reveal the effects and mechanisms of dissolved organic matter (DOM) on the adsorption of copper ions by suspended sediment particles, a Cu(Ⅱ) adsorption test was conducted through a laboratory simulation test. The results showed that DOM promoted the adsorption of Cu(Ⅱ) onto the suspended particles.

Laboratory and simulation study on the Cd(Ⅱ) adsorption by lake sediment: Mechanism and influencing factors.

Sediments are the major sinks for Cd(Ⅱ) in the aquatic environment. Here, the detailed binding mechanisms and effects of environmental factors on Cd(Ⅱ) adsorption onto lake sediment were tested by a batch of adsorption and characteristic experiments. Sediment samples and sediment-Cd complexes were characterized using Scanning electron microscopy, Energy dispersive spectroscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction spectral analyses.

Phosphate hinders the complexation of dissolved organic matter with copper in lake waters.

The properties of phosphate in lakes and their ability to cause eutrophication have been well studied; however, the effects of phosphate on the environmental behavior of other substances in lakes have been ignored. Dissolved organic matter (DOM) and heavy metals may coexist with phosphate in lakes. Herein, the mechanisms underlying the influence of phosphate on heavy metals complexation with DOM were investigated using multi-spectroscopic tools.

Restriction of dissolved organic matter on the stabilization of Cu(II) by phosphate.

The precipitation of Cu(II) by phosphate and the influence of dissolved organic matter (DOM) on the precipitation are essential for the fate of Cu(II) in aquatic environments. In this study, the influence of DOM on the reaction of phosphate with Cu(II) was investigated. Here, 51.

Enhanced Biosorption of Sb(III) onto Living Rhodotorula mucilaginosa Strain DJHN070401: Optimization and Mechanism.

How to effectively remove excess Sb(III) in the water environment by biosorption is receiving close attention in the international scientific community. To obtain the maximum biosorption efficiency, response surface methodology (RSM) was employed to optimize a total of 13 factors for biosorption of Sb(III) onto living Rhodotorula mucilaginosa DJHN070401. The mechanism of biosorption and bioaccumulation was also studied.