Recycling and Reuse of Spent LIBs: Technological Advances and Future Directions.

Recovering valuable metals from spent lithium-ion batteries (LIBs), a kind of solid waste with high pollution and high-value potential, is very important. In recent years, the extraction of valuable metals from the cathodes of spent LIBs and cathode regeneration technology are still rapidly developing (such as flash Joule heating technology to regenerate cathodes). This review summarized the studies published in the recent ten years to catch the rapid pace of development in this field.

Experimental study on adsorption of PbCl and CdCl on kaolin modified by leachates from municipal solid waste incineration power plant.

Six kinds of waste liquids produced in the treatment process of leachate in a waste incineration plant were used to improve the adsorption effect of raw kaolin on heavy metal chloride. The capture performances of these modified kaolin on PbCl and CdCl vapor were investigated in a two-stage fixed bed combustor. The results indicated that the adsorption effects of raw kaolin on PbCl and CdCl were improved in some experimental groups, main effective component was Na in the leachate, but the influences did not change regularly with the increase in the concentration of Na  introduced into kaolin.

High-temperature chlorination of PbO and CdO induced by interaction with NaCl and Si/Al matrix.

Municipal solid-waste incineration leads to emission of lead (Pb) and cadmium (Cd), which vaporize in furnace and condense in flue. NaCl in waste has been proven to enhance volatilization of Pb and Cd at high temperatures chlorination of oxides to chlorides; however, this process was not well-understood so far due to its complexity. This study decoupled the indirect chlorination process and direct chlorination process so that these two processes were investigated separately.

Typical Gaseous Semi-Volatile Metals Adsorption by Meta-Kaolinite: A DFT Study.

Kaolinite can be used as in-furnace adsorbent to capture gaseous semi-volatile metals during combustion, incineration, or gasification processes for the purposes of toxic metals emission control, ash deposition/slagging/corrosion inhibition, ultrafine particulate matter emission control, and so on. In this work, the adsorptions of typical heavy metals (Pb and Cd) and typical alkali metals (Na and K) by meta-kaolinite were investigated by the DFT calculation. The adsorption energies followed the sequence of NaOH-Si surface > KOH-Si surface > PbO-Al surface ≈ CdO-Al surface ≈ NaOH-Al surface > KOH-Al surface > NaCl-Al surface ≈ Na-Si surface > Na-Al surface > KCl-Al surface > Pb-Al surface > PbCl₂-Al surface > CdCl₂-Al surface ≈ K-Si surface ≈ PbCl-Al surface > K-Al surface > CdCl-Al surface > NaCl-Si surface > KCl-Si surface > Cd-Al surface.