Complexity and entropy of natural patterns.

Complexity and entropy play crucial roles in understanding dynamic systems across various disciplines. Many intuitively perceive them as distinct measures and assume that they have a concave-down relationship. In everyday life, there is a common consensus that while entropy never decreases, complexity does decrease after an initial increase during the process of blending coffee and milk.

Coupled analysis of arable land input intensity and output intensity based on sliding windows.

Sustainable intensification (SI) of agriculture can produce more food to meet the demand of a growing population while considering ecosystem health. The current SI estimation framework ignores the complex coupling between input and output intensity of arable land. A method for coupled analysis of arable land input intensity and output intensity based on sliding windows is proposed.

A gram-scale synthesis of very-long chain polyunsaturated fatty acids (VLC-PUFAs).

This manuscript describes our third generation, gram-scale synthesis of very long chain-polyunsaturated fatty acids (VLC-PUFAs), a unique and increasingly important class of lipids. Critical to this work and what makes it different from our previous approach to this family was the avoidance of oxidation sequences. Central to accomplishing this involved the use of a Negishi coupling reaction between the acid chloride derived from DHA and a saturated alkyl zinc reaction.

A raster-based spatial clustering method with robustness to spatial outliers.

Spatial clustering is an essential method for the comprehensive understanding of a region. Spatial clustering divides all spatial units into different clusters. The attributes of each cluster of the spatial units are similar, and simultaneously, they are as continuous as spatially possible.

Analyzing spatial patterns and driving factors of cropland change in China's National Protected Areas for sustainable management.

Farming in protected areas frequently challenges ecological conservation goals while supporting local livelihoods. To balance protection and agriculture, a comprehensive understanding of cropland dynamics in protected areas is of paramount importance. However, studies addressing this trade-off are relatively scarce, especially considering explicit Chinese government regulations on population relocation and cropland retirement in National Protected Areas (NPAs).

Impact of the new rural social pension insurance on the health of the rural older adult population: based on the China health and retirement longitudinal study.

The health issues of China's older adult population in rural areas have been receiving increasing attention with the continuous expansion of the nation's ageing population and the continuous promotion of urban-rural integration. The impact of the new rural social pension insurance (NRSPI) on the health of the rural older adult population, the mechanism of its action and how old-age service can be improved and optimised according to the health needs of the rural older adult population are urgent and realistic challenges. Based on survey data from the China Health and Retirement Longitudinal Study in 2015 and 2018, this study applies a multivariate ordered logistic regression model to explore the impact mechanism and effect of the NRSPI on the older adult population health in rural China while controlling for endogeneity.

The COVID-19 lockdown: a unique perspective into heterogeneous impacts of transboundary pollution on snow and ice darkening across the Himalayas.

The Tibetan Plateau holds the largest mass of snow and ice outside of the polar regions. The deposition of light-absorbing particles (LAPs) including mineral dust, black carbon and organic carbon and the resulting positive radiative forcing on snow (RFS) substantially contributes to glacier retreat. Yet how anthropogenic pollutant emissions affect Himalayan RFS through transboundary transport is currently not well known.

CLUMondo-BNU for simulating land system changes based on many-to-many demand-supply relationships with adaptive conversion orders.

Land resources are fundamentally important to human society, and their transition from one macroscopic state to another is a vital driving force of environment and climate change locally and globally. Thus, many efforts have been devoted to the simulations of land changes. Among all spatially explicit simulation models, CLUMondo is the only one that simulates land changes by incorporating the multifunctionality of a land system and allows the establishment of many-to-many demand-supply relationships.

Fulfilling global climate pledges can lead to major increase in forest land on Tibetan Plateau.

The UN Climate Change Conference in Glasgow spawned the enhancement and updating of many nations' climate pledges. Previous research has investigated the effects of these pledges on limiting planetary warming, but their spatially explicit effects on land use/cover are unknown. Here, we linked the Glasgow pledges and the spatially explicit responses of the Tibetan Plateau's land systems.

Sandwich-type CoSe-CNWs@rGO/S composites with efficient trapping and catalytic conversion of polysulfides in lithium-sulfur batteries.

Although lithium-sulfur batteries (LSBs) are very promising in energy storage devices, their low conductivity, shuttle effect, and volume expansion unfavorably lead to sluggish kinetics and worsening electrochemical performance. To address these problems, we firstly prepared conductive carbon nanowires embedded with lithiophilic CoSe nanoparticles (CoSe-CNWs), and utilized CoSe-CNWs to construct reduced graphene oxide (rGO) sheets; thereby, sandwich-type CoSe-CNWs@rGO composites were assembled. CoSe-CNWs@rGO composites were taken as the sulfur host.

The spatiotemporal variation in heavy metals in China's farmland soil over the past 20 years: A meta-analysis.

Accurate information on farmland soil heavy metal elements is needed for pollution management and strategic decision making at the national level. In this paper, we review the Chinese literature on soil heavy metal elements (i.e.

Biphenyl Cyclobutenone Photoelectrocyclizations.

In this work, we demonstrate that readily available conjugated bis-aryl cyclobutenones undergo photoelectrocyclization reactions to give the corresponding dihydrophenanthrene cyclobutanones when exposed to 350 nm light, TFA, and TMSCl. We have also found that cyclobutenone electrocyclizations and cycloreversions are in equilibrium.

Employing synergetic effect of ZnSe quantum dots and layered Ni(OH)to boost the performance of lithium-sulfur cathodes.

The low sulfur utilization, cycling instability, and sluggish kinetics are the critical obstructions to practical applications of lithium-sulfur batteries (LSBs). Constructing sulfur hosts with high conductivity, suppressed shuttle effect, and rapid kinetics is essential for their practical application in LSBs. Here, we synthetically utilized the merits of ZnSe quantum dots (QDs) and layered Ni(OH)to boost the performance of LSBs.

A special core-shell ZnS-CNTs/S@NH cathode constructed to elevate electrochemical performances of lithium-sulfur batteries.

Lithium-sulfur batteries (LSBs) are regarded as promising candidates for next-generation electrochemical energy storage systems due to their low cost and high energy density. However, the insulative sulfur, the volume expansion and high soluble polysulfides are three roots impeding their practical applications, and consequently bring challenges of low sulfur utilization, poor cyclic stability and sluggish redox kinetics. Herein, a special core-shell ZnS-CNTs/S@Ni(OH) (labeled as ZnS-CNTs/S@NH) cathode has been designed to overcome above obstacles and elevate the electrochemical performance.

The Coupled Impact of Emergency Responses and Population Flows on the COVID-19 Pandemic in China.

Coronavirus disease 2019 (COVID-19) has spread around the world and requires effective control measures. Like the human-to-human transmission of the severe acute respiratory syndrome-coronavirus 2 (SARS-CoV-2), the distribution of COVID-19 was driven by population flow and required emergency response measures to slow down its spread and degrade the epidemic risk. The local epidemic risk of COVID-19 is a combination of emergency response measures and population flow.

Use of Entropy in Developing SDG-based Indices for Assessing Regional Sustainable Development: A Provincial Case Study of China.

Sustainable development appears to be the theme of our time. To assess the progress of sustainable development, a simple but comprehensive index is of great use. To this end, a multivariate index of sustainable development was developed in this study based on indicators of the United Nations Sustainable Development Goals (SDGs).

Incorporation ZnS quantum dots into carbon nanotubes for high-performance lithium-sulfur batteries.

Constructing sulfur hosts with high electronic conductivity, large void space, strong chemisorption, and rapid redox kinetics is critically important for their practical applications in lithium-sulfur batteries (LSBs). Herein, by coupling ZnS quantum dots (QDs) with carbon nanotubes (CNTs), one multifunctional sulfur host CNT/ZnS-QDs is designed via a facile one-step hydrothermal method. SEM and TEM analyses reveal that small ZnS-QDs (<5 nm) are uniformly anchored on the CNT surface as well as encapsulated into CNT channels.

Dual-Wavelength Excited Intense Red Upconversion Luminescence from Er-Sensitized YO Nanocrystals Fabricated by Spray Flame Synthesis.

Er-sensitized upconversion nanoparticles (UCNPs) have attracted great attention due to their tunable upconversion (UC) emissions, low cytotoxicity, high resistance to photobleaching and especially multiple effective excitation wavelengths. However, detailed energy conversion between Er and Tm ions in YO UCNPs is still a problem, especially under multi-wavelength and variable pulse width excitation. In this work, we successfully fabricated a series of Er-sensitized YO nanocrystals by a spray flame synthesis method with a production rate of 40.

Photoelectrocyclization Reactions of Conjugated Cycloalkenones: Scope and Reactivity.

Outlined here are studies exploring the scope of the sequential photoelectrocyclization, [1,5]-hydride shift of conjugated bis-aryl cycloalkenone substrates. We have found not only that the cyclization precursors can be synthesized in a modular fashion but also that the cyclization is efficient and amenable to the presence of a range of cycloalkenones and aromatic systems. Among the interesting discoveries from this work is that the electrocyclization intermediate can be competitively captured with protons and that the nature of the excited state (singlet vs triplet) is dependent on aromatic substitution.

Stereodivergent Photoelectrocyclization Reactions of Bis-aryl Cycloalkenones: Intercepting Photoelectrocyclization Intermediates with Acid.

Described here are tandem photoelectrocyclization and [1,5]-hydride shift reactions of heteroaryl-containing bis-aryl cyclohexenone derivatives that give heteroaryl-substituted dihydrophenanthrenes. This Letter demonstrates that electrocyclization intermediates can be trapped with acid when the [1,5]-hydride shift is relatively slow. From a practical perspective, the observation that the acid-mediated reaction gives a divergent stereochemical outcome when compared with the reaction run under neutral conditions makes these transformations powerful.

Air pollution exposure associates with increased risk of neonatal jaundice.

Clinical experience suggests increased incidences of neonatal jaundice when air quality worsens, yet no studies have quantified this relationship. Here we reports investigations in 25,782 newborns showing an increase in newborn's bilirubin levels, the indicator of neonatal jaundice risk, by 0.076 (95% CI: 0.

Self-Assembled Vanadium Oxide Nanoflakes for p-Type Ammonia Sensors at Room Temperature.

VO₂(B), VO₂(M), and V₂O₅ are the most famous compounds in the vanadium oxide family. Here, their gas-sensing properties were investigated and compared. VO₂(B) nanoflakes were first self-assembled via a hydrothermal method, and then VO₂(M) and V₂O₅ nanoflakes were obtained after a heat-phase transformation in nitrogen and air, respectively.

Is Himalayan-Tibetan Plateau "drying"? Historical estimations and future trends of surface soil moisture.

The Himalayan-Tibetan Plateau (HTP), often known as the "Third Pole" and the "Asian Water Tower", is the source of water resources for many Asian rivers and in turn for hundreds of millions of people living downstream. The HTP has direct impacts on the establishment and maintenance of Asian monsoon, and therefore on the climate of its surrounding areas. Besides, soil moisture plays a critical role in the hydrological cycle and is a critical link between land surface and atmosphere.