Progress in Polyurethane and Composites.

Polyurethane materials have received increasing attention as daily materials due to their unique structures and properties [...

A Novel Polyfunctional Polyurethane Acrylate Derived from Castor Oil-Based Polyols for Waterborne UV-Curable Coating Application.

Because of its unique molecular structure and renewable properties, vegetable oil has gradually become the focus of researchers. In this work, castor oil was first transformed into a castor oil-based triacrylate structure (MACOG) using two steps of chemical modification, then it was prepared into castor oil-based waterborne polyurethane acrylate emulsion, and finally, a series of coating materials were prepared under UV curing. The results showed that with the increase in MACOG content, the glass transition temperature of the sample was increased from 20.

Effect of modified bamboo lignin replacing part of C5 petroleum resin on properties of polyurethane/polysiloxane pressure-sensitive adhesive and its application on the wood substrate.

This paper reports a fresh and robust strategy to develop polyurethane/polysiloxane pressure-sensitive adhesives (PSAs) with excellent properties by replacing part of C5 petroleum resin with modified lignin. A unique aspect of this work is the use of renewable lignin to obtain modified monomers. The phenolic hydroxyl group of lignin is increased by 21.

Evolution properties of the radially polarized Laguerre-Gaussian-correlated Schell-model beams propagating in uniaxial crystals.

In this paper, we discuss, both analytically and numerically, the paraxial propagation of the radially polarized Laguerre-Gaussian-correlated Schell-model (LGCSM) beams orthogonal to the optical axis in uniaxial crystals. The analytical expression for the cross-spectral density function and the second-order moments of the radially polarized LGCSM beams are derived, and the evolution properties of the normalized intensity distribution, the spectral degree of the coherence (SDOC), and the spectral degree of the polarization (SDOP) in uniaxial crystals are elucidated by numerical examples. It is found that the intensity distribution of the radially polarized LGCSM beams evolves from a doughnut shape into a solid shape and finally converts into an elliptical symmetric hollow-ring profile in uniaxial crystals due to the combined effect of special correlation functions and the anisotropy effect of the uniaxial crystals.

Seawater-enhanced tough agar/poly(N-isopropylacrylamide)/clay hydrogel for anti-adhesion and oil/water separation.

Hydrogels as typical hydrophilic materials are promising candidates for designing novel functional materials for anti-fouling, oil/water separation, wearable devices, tissue scaffolds, etc. However, it still remains a challenge to design stable and tough hydrogels for applications in complex environments of high stress, temperature, salt, and pH. Herein, we fabricate a novel seawater-enhanced Agar/Poly(N-isopropylacrylamide)/clay hydrogel (APNC gel) through a facile photo-initiated polymerization process.

Propagation properties of partially coherent crescent-like beams under maritime environment.

Based on the extended Huygens-Fresnel principle, the analytical expressions for the intensity distribution, effective radius of curvature, beam wander, Strehl ratio, and the power in the bucket of a partially coherent crescent-like (PCCL) beam under the maritime environment are derived. The propagation properties of the PCCL beams through the maritime environment are investigated in detail. Numerical results indicate that, for the maritime environment, the propagation properties and beam quality of a PCCL beam are closely related to its initial beam parameters and the turbulence parameters.

Biosynthetic bifunctional enzyme complex with high-efficiency luciferin-recycling to enhance the bioluminescence imaging.

Firefly luciferase is a prominent reporter on molecular imaging with the advantage of longer wavelength on light emission and the ATP linear correlation, which makes it useful in most of current bioluminescence imaging model. However, the utility of this biomaterial was limited by the signal intensity and stability which are respectively affected by enzyme activity and substrate consumption. This study demonstrated a series of novel synthetic bifunctional enzyme complex of Firefly luciferase (Fluc) and Luciferin-regenerating enzyme (LRE).

Fusion expression of bifunctional enzyme complex for luciferin-recycling to enhance the luminescence imaging.

Firefly luciferase (Fluc) has been widely used as a bioluminescent monitor. The ATP linear correlation and exogenous luciferin requirement make it useful in most of current imaging systems. However, the utility of this reporter was still limited by the intensity and decay of the luminescent signal, and the active site and structure of enzyme including the relevant substrate channeling region.