Caffeine Encapsulation in Metal Organic Framework MIL-53(Al) at Pilot Plant Scale for Preparation of Polyamide Textile Fibers with Cosmetic Properties.

Currently in the marketplace, we can find clothing items able to release skin-friendly ingredients while wearing them. These innovative products with high-added value are based on microencapsulation technology. In this work, due to its lightness, flexibility, porosity, chemical affinity and adsorption capacity, metal-organic framework (MOF) MIL-53(Al) was the selected microcapsule to be synthesized at a large scale and subsequent caffeine encapsulation.

Study of Melamine-Formaldehyde/Phase Change Material Microcapsules for the Preparation of Polymer Films by Extrusion.

n-Eicosane-melamine formaldehyde microcapsules of an average size of 1.1 μm and latent heat of fusion of 146.2 ± 5.

CAF@ZIF-8: one-step encapsulation of caffeine in MOF.

Two strategies for encapsulating caffeine in ZIF-8 were carried out in this work: (1) one-step, in situ encapsulation where caffeine is added to a ZIF-8 synthesis solution and the MOF structure is formed around the entrapped molecule; and (2) ex situ encapsulation whereby caffeine is put into contact with previously synthesized or purchased ZIF-8. The products obtained were analyzed with XRD, TGA, Vis-UV, GC-MS, FTIR, (13)C NMR, and N 1s XPS to compare both encapsulation methods. Chemical and structural evidence indicated that the preferential adsorption site of caffeine molecules inside the ZIF-8 structure is near the methyl and CH groups of 2-methylimidazole ligand.