In this work, the hexane, chloroform, and methanol extracts from were utilized to green-synthesize silver nanoparticles (Kf-, Kf-, and Kf-AgNPs). The Kf-, Kf-, and Kf-AgNPs were characterized by spectroscopy and microscopy techniques. The antibacterial activity of AgNPs was studied against bacteria strains, utilizing the microdilution assay.
View Article and Find Full Text PDFKetorolac, a highly persistent NSAID of environmental concern, was significantly removed from water (80% removal) through photoelectrocatalysis where titanium dioxide nanotubes prepared by Ti foil electrochemical anodization at 30 V were used as photoanodes. Fifteen milligrams per liter of ketorolac solutions in a 0.05 M NaSO aqueous medium was subjected to irradiation from a 365-nm light with an intensity of 1 mWcm and under an applied potential of 1.
View Article and Find Full Text PDFMesostructured PbO/TiO materials were synthesized to perform electrocatalysis (as electrooxidation, EO) and photoelectrocatalysis for removing diclofenac (DCF), 15 ppm concentration in 0.1 M NaSO solutions, at different pH conditions (3.0, 6.
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December 2021
As surface-enhanced Raman spectroscopy (SERS) continues developing to be a powerful analytical tool for several probes, four important aspects to make it more accessible have to be addressed: low-cost, reproducibility, high sensibility, and recyclability. Titanium dioxide nanotubes (TiO NTs) prepared by anodization have attracted interest in this field because they can be used as safe solid supports to deposit metal nanoparticles to build SERS substrate nanoplatforms that meet these four desired aspects. TiO NTs can be easily prepared and, by varying different synthesis parameters, their dimensions and specific features of their morphology can be tuned allowing them to support metal nanoparticles of different sizes that can achieve a regular dispersion on their surface promoting high enhancement factors (EF) and reproducibility.
View Article and Find Full Text PDFThe electrochemical removal of the 1-chloro-2,4-dinitrobenzene (DNCB) herbicide, a potentially carcinogenic agent from aqueous solutions, was performed at PbO and BDD electrodes by bulk electrolysis under galvanostatic control (300 and 400 A m) and under two pH conditions (3 and 9). Results clearly indicated that a 62 % of mineralization was achieved with BDD anode at pH 3, while only a 46 % of electrochemical oxidation (EO) was achieved at PbO electrode. The mineralization current efficiency (MCE) depended on the electrode material, current density, and pH conditions; but, for both PbO and BDD, high MCE was achieved at pH 3 and 300 A m, obtaining 2.
View Article and Find Full Text PDFHospitals consume a large amount of water, so they also generate large amounts of wastewater, which contain a wide variety of contaminants. It is important to consider that hospital effluents are a mixture of pollutants that can interact with each other and have a negative impact on aquatic species of water bodies. The aim of this study was to evaluate the effects induced by a hospital effluent using Danio rerio embryos.
View Article and Find Full Text PDFThe anodic oxidation of methamidophos (MMD), a highly toxic pesticide used worldwide, was studied in a sodium sulfate aqueous solution on Pb/PbO2, Ti/SnO2, and Si/BDD (boron doped diamond) electrodes at 30 degrees C. Under galvanostatic conditions, it was observed thatthe performance of the electrode material is influenced by pH and current density as shown by HPLC and ATR-FTIR analysis of MMD and its oxidation products along the electrolysis. It was found that MMD degradation using Pb/PbO2 in acid media (pH 2.
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