Potential of water sediments in construction materials: Current approaches and critical consideration of future challenges.

Human activities result in sediment accumulation, so the reservoirs gradually lose their functionality, impacting their ability to manage large flood inflows, supply water, and generate hydroelectric power. Therefore, periodic removal of sediments from water reservoirs is essential to maintain functionality. Notwithstanding, the management of dredged sediments is a multifaceted process that involves careful consideration of environmental, regulatory, and economic factors to ensure their responsibility and sustainable handling.

Mechanical Synthesis and Calorimetric Studies of the Enthalpies of Formation of Chosen Mg-Pd Alloys.

Despite many years of research and continuous improvements in scientific equipment, some of the thermodynamic properties of binary systems are still unknown, or are only theoretically predicted or calculated. This situation often arises from the difficulties in preparing alloys for experimental measurements. The alloys from the Mg-Pd system, especially for the Pd-rich side, are difficult to produce, and the availability of thermodynamic data is very limited.

The novel incorporation of lignin-based systems for the preparation of antimicrobial cement composites.

This paper, for the first time, presents a potential application of titanium(IV) oxide and silicon(IV) oxide combined with lignin through a solvent-free mechanical process as admixtures for cement composites. The designed TiO-SiO (1:1 wt./wt.

The comparison between intratympanic gentamicin prehabilitation and postoperative virtual reality exposure to standard vestibular training in patients with vestibular schwannoma.

Objective: Resection of the vestibular schwannoma causes acute peripheral vestibular loss. The process of central compensation starts immediately afterward. The rehabilitation goal is to support this process and restore the quality of life.

Consequences of omitting some important factors in the environmental analyses of commercial sodium silicate/sodium hydroxide use for alkaline activation in the light of comparison with cement-based composites.

Alkali-activated materials (AAMs) based on various waste precursors were considered mostly as a sustainable alternative to Portland cement-based composites to date. However, a narrow focus on carbon dioxide savings in the environmental assessment of AAMs may not be sufficient to achieve a truly sustainable solution. Therefore, this paper provides a detailed insight into midpoint impact categories related to the production of AAMs based on waste precursors and conventional activators, as compared with common cement-based materials.

Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation.

One of the biggest challenges in the construction industry in recent times is the mitigation of the environmental impact of this sector, the reduction in dependence on primary raw materials, and the reduction in CO production while maintaining functional properties. Alkaline activation of a number of waste products represents a promising way to achieve the above-mentioned goals, but the availability of a number of waste products changes over time, especially in Europe. While freshwater sediments were in the past widely utilized as an agricultural fertilizer, recent precautions have significantly decreased such application, and thus new destinations must be delivered.

Mirror visual feedback as therapeutic modality in unilateral upper extremity complex regional pain syndrome type I: randomized controlled trial.

Background: There is growing evidence for the effectiveness of mirror therapy (MT) on pain reduction in patients with type I complex regional pain syndrome (CRPS I).

Aim: To evaluate the efficacy of MT on pain reduction and hand function in subjects with unilateral upper extremity CRPS I.

Design: Randomized controlled trial with control group cross-over (half cross-over design).

Ecotoxicity of Caffeine as a Bio-Protective Component of Flax-Fiber-Reinforced Epoxy-Composite Building Material.

Caffeine is a verified bio-protective substance in the fight against the biodegradation of cellulose materials, but its ecotoxicity in this context has not yet been studied. For this reason, the ecotoxicity of flax-fiber-reinforced epoxy composite with or without caffeine was tested in the present study. Prepared samples of the composite material were tested on freshwater green algal species (), yeasts (), and crustacean species ().

Anomalous Impact of Mechanochemical Treatment on the Na-ion Conductivity of Sodium Closo-Carbadodecaborate Probed by X-Ray Raman Scattering Spectroscopy.

Solid-state sodium ion conductors are crucial for the next generation of all-solid-state sodium batteries with high capacity, low cost, and improved safety. Sodium closo-carbadodecaborate (NaCB H ) is an attractive Na-ion conductor owing to its high thermal, electrochemical, and interfacial stability. Mechanical milling has recently been shown to increase conductivity by five orders of magnitude at room temperature, making it appealing for application in all-solid-state sodium batteries.

Pre-mandibular pharyngeal pouches in early non-teleost fish embryos.

The vertebrate pharynx is a key embryonic structure with crucial importance for the metameric organization of the head and face. The pharynx is primarily built upon progressive formation of paired pharyngeal pouches that typically develop in post-oral (mandibular, hyoid and branchial) domains. However, in the early embryos of non-teleost fishes, we have previously identified pharyngeal pouch-like outpocketings also in the pre-oral domain of the cranial endoderm.

Experimental and Environmental Analysis of High-Strength Geopolymer Based on Waste Bricks and Blast Furnace Slag.

The rationalization of material flows, together with the utilization of waste raw materials for the production of alternative binders, became a very attractive topic during the last decades. However, the majority of designed materials can be used as a replacement for low-performance products. In this work, the waste materials (brick powder and blast furnace slag) are valorized through geopolymerization to design high-performance material as an alternative to high-performance concrete.

Does vestibular function correlate with objective MRI findings after vestibular schwannoma surgery?

Objective: Vestibular schwannoma surgery leads to acute unilateral vestibular loss. In some patients, however, the process of post-operatively initiated central compensation proceeds more rapidly than in others. This study aimed to evaluate post-operative vestibular function and correlate it with morphological findings of MRI scans.

Elucidating the pressure-induced enhancement of ionic conductivity in sodium -hydroborate electrolytes for all-solid-state batteries.

Unlabelled: Hydroborates are an emerging class of solid electrolytes for all-solid-state batteries. Here, we investigate the impact of pressure on the crystal structure and ionic conductivity of a close-hydroborate salt consisting of NaBH and NaBH. Two NaBH:NaBH ratios were studied, 1:1 and 1:3.

Near-Infrared Spectroscopy as a Tool for Simultaneous Determination of Diesel Fuel Improvers.

Diesel and biodiesel blends requires additives to improve fuel quality properties and engine performance. Diesel improvers are added before, during and/or after the fuel is blended. However, no accurate rapid and non-destructive analytical method is used during the fuel production that could determine the exact concentration of various types of improvers in diesel fuel.

The Development of Shyness from Late Childhood to Adolescence: A Longitudinal Study of Mexican-origin Youth.

Shyness, the tendency to be inhibited and uncomfortable in novel social situations, is a consequential personality trait, especially during adolescence. The present study examined the development of shyness from late childhood (age 10) through adolescence (age 16) using data from a large, longitudinal study of Mexican-origin youth ( = 674). Using both self- and mother-reports of shyness assessed via the , we found moderate to high rank-order stabilities across two-year intervals and a mean-level decrease in shyness from age 10 to 16.

Trinuclear Magnesium Imidazolate Borohydride Complex.

A new type of hybrid compound, combining properties of MOFs and borohydrides, was synthesized solvothermally using Mg(BH) and imidazole as precursors. Material in the form of acetonitrile solvate with formula [Mg{(Im)BH(Im)}(ImH)]·CHCN crystallizes in the space group 3̅, having the unit cell parameters = 15.1942(2) Å and = 28.

Abrupt change from moderate positive to colossal negative thermal expansion caused by imidazolate composite formation.

Unlabelled: This work describes temperature-induced crystallization processes and reaction mechanisms occurring in the borohydride-imidazolate system. In the course of thermal evolution, crystal structures of two novel bimetallic imidazolates AMnIm (A = Na, K) were solved using synchrotron radiation powder diffraction data. Both the alkali metal cation and the Mn cations exhibit distorted octahedral coordination while each imidazolate is surrounded by two alkali metal and two manganese atoms.

Ecotoxicity and Biodegradation of Sustainable Environment-Friendly Bone-Glue-Based Adhesive Suitable for Insulation Materials.

Bone glue with sodium lignosulfonate is a protein-based adhesive. Their combination leads to strong binding necessary for the achievement of adhesive properties. However, biodegradation and ecotoxicity of materials composed of bone glue and sodium lignosulfonate has never been studied before.

Structural Performance of Lightweight Aggregate Concrete Reinforced by Glass or Basalt Fiber Reinforced Polymer Bars.

Lightweight aggregate concrete (LWC) and fiber reinforced polymer (FRP) reinforcement are potentially more sustainable alternatives to traditional steel-reinforced concrete structures, offering several important benefits. To further the knowledge in this area, the physical-mechanical properties of LWC produced with 0%, 50%, and 100% expanded clay aggregate were assessed. Subsequently, the flexural behavior of LWC beams reinforced with steel reinforcement and glass and basalt FRP bars was tested.

Bond Behavior of FRP Bars in Lightweight SCC under Direct Pull-Out Conditions: Experimental and Numerical Investigation.

In recent decades, lightweight aggregate concrete (LWC) became a popular building material due to its desired properties. However, various attributes of LWC, such as bond behavior of used reinforcing, have not been described thoroughly. In this regard, LWC produced with 0%, 50%, and 100% expanded clay aggregate was designed, and the physical-mechanical properties were assessed for material characterization.

Waste brick dust as a prospective eco-friendly alternative component of artificial soils for ecotoxicological studies.

Current artificial soils for ecotoxicological studies contain non-renewable materials that must be mined, and their production and processing consume a lot of energy and generate a significant amount of carbon dioxide (CO). In this paper, waste brick dust is proposed as an alternative to calcium carbonate (CaCO), which is used for pH adjustment of the Organization for Economic Co-operation and Development (OECD) soils. The artificial soils containing brick dust are contaminated with boric acid as a reference substance in the concentration range of 100-500 mg/kg and studied in the tests with enchytraeids (E.

Environmental Consequences of Rubber Crumb Application: Soil and Water Pollution.

End-of-life tires are utilized for various purposes, including sports pitches and playground surfaces. However, several substances used at the manufacture of tires can be a source of concerns related to human health or environment's adverse effects. In this context, it is necessary to map whether this approach has the desired effect in a broader relation.