Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex.

Treatment of 1,3-bis(3'-butylimidazolyl-1'-yl)benzene diiodide with elemental sulfur in the presence of a base produced a bis(N-heterocyclic thione) (NHT) pincer ligand precursor. Its reaction with PdCl2(CH3CN)2 produced chloro[1,3-bis(3'-butylimidazole-2'-thione-κ-S)benzene-κ-C]palladium(ii), a 6,6-fused ring SCS-NHT palladium pincer complex. This air stable compound is, to our knowledge, the first SCS pincer complex that utilizes N-heterocyclic thione (NHT) donor groups.

Synthesis of polymeric ladders by topochemical polymerization.

Two polymeric ladders were synthesized by topochemical polymerization. The critical assemblies with multiple reactive centers were characterized by single crystal X-ray diffraction. Approximately 64% and 70% of the mass of the two polymeric ladders can be derived from biomass, respectively.

A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate.

A flexible organic sheet spontaneously assembled under mild conditions from a tri-carbamate. By introducing cyclohexyl side chains as 'pillars' between the sheets, a hydrogen bonded organic framework was formed which displayed a capacity for accommodating and releasing guest molecules. The guest size/shape selectivity of the lamellar framework was demonstrated by testing with various guests.