Publications by authors named "Caroline S Lee"

This study introduces a post-treatment process, the subpressure-driven soft deformation method, to reduce inherent voids in Material Extrusion (MEX) components. By subjecting printed green components to heat treatment under subpressure, the process enhances viscosity, effectively filling voids formed between deposited tracks. The average porosities of the samples sintered from the green components without and with soft deformation are calculated to be 3.

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One of the main gaseous pollutants released by chemical production industries are benzene, toluene and xylene (BTX). These dangerous gases require immediate technology to combat them, as they put the health of living organisms at risk. The development of heterogeneous photocatalytic oxidation technology offers several viewpoints, particularly in gaseous-phase decontamination without an additional supply of oxidants in air at atmospheric pressure.

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Pain from bacterial infection was believed to be the consequence of inflammation induced by bacterial products. However recent studies have shown that bacterial products can directly activate sensory neurons and induce pain. The mechanisms by which bacteria induce pain are poorly understood, but toll-like receptor (TLR)4 and transient receptor potential A1 (TRPA1) receptors are likely important integrators of pain signaling induced by bacteria.

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Green energy production is becoming increasingly important in mitigating the effects of climate change, and the photocatalytic approach could be a potential solution. However, the main barriers to its commercialization are ineffective catalysis due to recombination, poor optical absorption, and sluggish carrier migration. Here, we fabricated a two-dimensional (2D) reduced niobium oxide photocatalyst synthesized by an thermal method followed by copper incorporation.

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Volume loading of feedstock using trimodal iron (Fe) powders was investigated for the application of extrusion-based additive manufacturing (AM). Fe trimodal powder composed of nano, sub-nano, and micro particles was manufactured via the powder metallurgy process where small particles behave as rolling bearings among large particles, and thereby improving the flow characteristics of feedstock by minimizing friction among the particles. The flow behavior and microstructures of the monomodal feedstock were compared with those of the trimodal feedstock.

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A quartet dual-band electrochromic device (ECD) was developed to selectively control the transmittance from the visible to near-infrared wavelengths for the application of an energy-efficient smart window. The new AgNO+TBABr+LiClO (ATL)-based electrolyte was developed to independently control the redox reaction of lithium and silver ions to demonstrate the quartet mode of an ECD. A dual-band ECD with a sandwich structure was assembled using an ATL-based electrolyte, WO electrochromic layer, and antimony-doped tin oxide (ATO) ion storage layer.

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Herein, a full spectrum-induced hybrid structure consisting of one-dimensional nickel titanate (NiTiO) nanofibers (NFs) decorated by petal-like molybdenum disulfide (MoS) particles was designed through a facile hydrothermal method. The key parameters for tailoring the morphology and chemical, surface, and interfacial properties of the heterostructure were identified for efficient and selective conversion of CO into valuable chemicals. Introducing MoS layers onto NiTiO NFs provided superior CO conversion with significantly higher yields.

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Learning about temporal structure is adaptive because it enables the generation of expectations. We examined how the brain uses experience in structured environments to anticipate upcoming events. During fMRI (functional magnetic resonance imaging), individuals watched a 90 s movie clip six times.

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Crystallization via an amorphous pathway is often preferred by biologically driven processes enabling living species to better regulate activation energies to crystal formation that are intrinsically linked to shape and size of dynamically evolving morphologies. Templated ordering of 3-dimensional space around amorphous embedded non-equilibrium phases at heterogeneous polymer─metal interfaces signify important routes for the genesis of low-dimensional materials under stress-induced polymer confinement. We report the surface induced catalytic loss of P=O ligands to bond activated aromatization of C-C C=C and Ti=N resulting in confinement of porphyrin-TiO within polymer nanocages via particle attachment.

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In many low income developing countries, socioeconomic, environmental and demographic factors have been linked to around half of the disease related deaths that occur each year. The aim of this study is to investigate the sociodemographic factors, mother and child health status, water, sanitation, and hygienic conditions of a Nepalese community residing in a hilly rural village, and to identify factors associated with mother and child health status and the occurrence of diarrheal and febrile disease. A community-based cross-sectional survey was carried out and 315 households from the village of Narjamandap were included in this study.

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Ternary structures consisting of hollow g-CN nanofibers/MoS/sulfur, nitrogen-doped graphene and bulk g-CN (TCN) were designed as a dual layered film and fabricated using a spin-coating method. The first ternary structures were spin-coated on fluorine-doped tin oxide (FTO) glass, followed by spin-coating of g-CN film to form dual layers. We characterized the microstructural morphologies, chemical composition/bonding and optical properties of the dual layered film and observed significantly reduced recombination rates of photo-induced electron-hole pairs due to effective separation of the charge carriers.

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Herein, we newly design a ternary structure of 1-dimensional hollow g-C3N4 nanofibers (HGCNF) decorated with molybdenum disulfide (MoS2) and sulfur/nitrogen-doped graphene (SNG) via a one-pot hydrothermal treatment at relatively low temperature. The firstly presented HGCNF are fabricated using electrospinning followed by the thermal sintering method. After that, MoS2 is grown onto HGCNF, while SNG covered the structures during the hydrothermal method.

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We engineered high aspect ratio FeO nanorods (with an aspect ratio of 17 : 1) coated with g-CN using a sequential solvothermal method at very low temperature followed by a thermal evaporation method. Here, the high aspect ratio FeO nanorods were directly grown onto the FTO substrate under relatively low pressure conditions. The g-CN was coated onto a uniform FeO nanorod film as the heterostructure, exhibiting rational band conduction and a valence band that engaged in surface photoredox reactions by a direct z-scheme mechanism.

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Sensory neurons innervating the dental pulp have unique morphological and functional characteristics compared to neurons innervating other tissues. Stimulation of dental pulp afferents whatever the modality or intensity of the stimulus, even light mechanical stimulation that would not activate nociceptors in other tissues, produces an intense pain. These specific sensory characteristics could involve receptors of the Transient Receptor Potential channels (TRP) family.

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We report the coating of metal-free graphitic carbon nitride (g-C3N4) onto titanium dioxide (TiO2) nanorods via a thermal evaporation method. Prior to g-C3N4 coating, TiO2 nanoclusters were grown on TiO2 nanorods to enhance the surface area by dipping in a TiCl3 solution for 12, 24 and 36 h. The prepared films were analyzed to assess the improvement in absorbance and reduction in recombination losses.

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Titanium dioxide (TiO) with exposed (001) facets (TiO(001)) has attractive photocatalytic properties. However, the high recombination rate of the photo-excited charge carriers on this surface often limits its application. Here, we report that a few-layered 1T-MoS coating on TiO(001) nanosheets (abbreviated as MST) can be a promising candidate that overcomes some of the challenges of TiO(001).

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Understanding the complex world of material growth and tunability has mystified the minds of material scientists and has been met with increasing efforts to close the gap between controllability and applicability. The reality of this journey is frustratingly tortuous but is being eased through better conceptual appreciation of metal crystalline frameworks that originate from shape and size dependent solvent responsive growth patterns. The quantum confinement of TiO in the range of 0.

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A one-dimensional (1D) nanostructure having a porous network is an exceptional photocatalytic material to generate hydrogen (H2) and decontaminate wastewater using solar energy. In this report, we synthesized nanoporous 1D microrods of graphitic carbon nitride (g-C3N4) via a facile and template-free chemical approach at room temperature. The use of concentrated acids induced etching and lift-off because of strong oxidation and protonation.

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Background: HIV-1 integration is prone to a high rate of failure, resulting in the accumulation of unintegrated viral genomes (uDNA) in vivo and in vitro. uDNA can be transcriptionally active, and circularized uDNA genomes are biochemically stable in non-proliferating cells. Resting, non-proliferating CD4 T cells are prime targets of HIV-1 infection and latently infected resting CD4 T cells are the major barrier to HIV cure.

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Unlabelled: HIV-1 infection leads to the progressive depletion of the CD4 T cell compartment by various known and unknown mechanisms. In vivo, HIV-1 infects both activated and resting CD4 T cells, but in vitro, in the absence of any stimuli, resting CD4 T cells from peripheral blood are resistant to infection. This resistance is generally attributed to an intracellular environment that does not efficiently support processes such as reverse transcription (RT), resulting in abortive infection.

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Since direct printing technology has developed intensively, low-cost fabrication and reliability have become critical challenges for mass production of printed electronic devices. The silver/copper (Ag/Cu) nanopaste was manufactured by Ag nanopaste mixed with different proportions of Cu nanoparticles ranging from 0 to 5 vol.% in order to investigate the influences of Cu content on the electrical properties and electrochemical migration (ECM) characteristics.

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HIV-1 hijacks and disrupts many processes in the cells it infects in order to suppress antiviral immunity and to facilitate its replication. Resting CD4 T cells are important early targets of HIV-1 infection in which HIV-1 must overcome intrinsic barriers to viral replication. Although resting CD4 T cells are refractory to infection in vitro, local environmental factors within lymphoid and mucosal tissues such as cytokines facilitate viral replication while maintaining the resting state.

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Graphitic carbon nitride (g-C3N4) was hybridized with CdS nanoparticles and reduced graphene oxide (RGO) sheets using a facile chemical method, for the application of catalytic photodegradation of Rhodamine B and Congo red dyes under irradiation with UV and visible light. Fourier-transform infrared (FTIR) spectroscopy and X-ray photoemission spectroscopy (XPS) analyses confirmed the formation of pure g-C3N4, as well as g-C3N4/CdS, g-C3N4/RGO, and g-C3N4/CdS/RGO composites. The large surface area of the g-C3N4/CdS/RGO composite (70.

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Article Synopsis
  • - Researchers developed a simpler method to fabricate TiO2 layers for dye-sensitized solar cells (DSSCs) by using a nano-particle deposition system (NPDS), eliminating the complex steps of traditional paste-based methods.
  • - This new method involves spraying nanocrystalline TiO2 powders of varying sizes directly onto transparent conductive oxide (TCO) glass, which enhances the layer's porosity and light scattering properties.
  • - The study found that DSSCs created with a mix of different particle sizes performed better than those using a single particle size, indicating that the NPDS method improves solar cell efficiency and is adaptable to flexible substrates at room temperature.
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