Particle atomic layer deposition (ALD) is an emerging method for engineering 3D materials, such as powders, for energy applications. In our study, we employ a commercially available and scalable particle ALD system to synthesize Pt/C electrocatalysts for fuel cells. Our method yields Pt/C catalysts characterized by highly dispersed platinum nanoparticles with a narrow particle size distribution of 2.
View Article and Find Full Text PDFIntegrated reference electrodes allow to deconvolute voltage contributions of anode and cathode and contribute to a better understanding of CO electrolyzers. However, in zero-gap cell configurations, this integration can be challenging and obtaining error-free data with such a setup is a non-trivial task. This study compares five different methods to integrate a reference electrode into an alkaline zero-gap CO electrolysis cell.
View Article and Find Full Text PDFThe design of catalysts with stable and finely dispersed platinum or platinum alloy nanoparticles on the carbon support is key in controlling the performance of proton exchange membrane (PEM) fuel cells. In the present work, an intermetallic PtCo/C catalyst is synthesized double-passivation galvanic displacement. TEM and XRD confirm a significantly narrowed particle size distribution for the catalyst particles compared to commercial benchmark catalysts (Umicore PtCo/C).
View Article and Find Full Text PDFThe integrated stress response (ISR) tunes the rate of protein synthesis. Control is exerted by phosphorylation of the general translation initiation factor eIF2. eIF2 is a guanosine triphosphatase that becomes activated by eIF2B, a two-fold symmetric and heterodecameric complex that functions as eIF2's dedicated nucleotide exchange factor.
View Article and Find Full Text PDFWe have observed long-range spin-triplet supercurrents in Josephson junctions containing ferromagnetic (F) materials, which are generated by noncollinear magnetizations between a central Co/Ru/Co synthetic antiferromagnet and two outer thin F layers. Here we show that the spin-triplet supercurrent is enhanced up to 20 times after our samples are subject to a large in-plane field. This occurs because the synthetic antiferromagnet undergoes a "spin-flop" transition, whereby the two Co layer magnetizations end up nearly perpendicular to the magnetizations of the two thin F layers.
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