Experimental and Computational Evidence of the Biradical Structure and Reactivity of Titanium(IV) Enolates.

Quantum chemical calculations have unveiled the unexpected biradical character of titanium(IV) enolates from N-acyl oxazolidinones and thiazolidinethiones. The electronic structure of these species therefore involves a valence tautomerism consisting of an equilibrium between a closed shell (formally Ti(IV) enolates) and an open shell, biradical, singlet (formally Ti(III) enolates) electronic states, whose origin is to be basically found in changes of the Ti-O distance. Spectroscopic studies of the intermediate species lend support to such a model, which also turns out to be crucial for a better understanding of the overall reactivity of titanium(IV) enolates.

In-band optical signal-to-noise ratio monitoring method based on high-resolution polarization analysis and induced differential group delay.

We report on an in-band optical signal-to-noise ratio monitoring technique for wavelength division multiplexed channels. Our proposal relies on the different degree of polarization between the signal (highly polarized) and the noise (not polarized). Using this principle, we divide the signal under test into two orthogonal polarization components and induce a differential group delay via a controlled birefringence apparatus that produces a wavelength-dependent shift of the polarization state of the signal.