Safflorite, (Co,Ni,Fe)As(2), isomorphous with marcasite.

Safflorite, a naturally occurring cobalt-nickel-iron diarsenide (Co,Ni,Fe)As(2), possesses the marcasite-type structure, with cations (M = Co + Ni + Fe) at site symmetry 2/m and As anions at m. The MAs(6) octa-hedra share two edges, forming chains parallel to c. The chemical formula for safflorite should be expressed as (Co,Ni,Fe)As(2), rather than the end-member format CoAs(2), as its structure stabilization requires the simultaneous inter-action of the electronic states of Co, Ni, and Fe with As(2) (2-) dianions.

Iranite, CuPb10(CrO4)6(SiO4)2(OH)2, isomorphous with hemihedrite.

This study presents the first structural report of iranite, ideally CuPb10(CrO4)6(SiO4)2(OH)2 [copper decalead hexachromate bis(orthosilicate) dihydroxide], based on single-crystal X-ray diffraction data. Iranite is isomorphous with hemihedrite, with substitution of Cu for Zn and OH for F. The Cu atom is situated at the special position with site symmetry 1.