Publications by authors named "Cara Manning"

Article Synopsis
  • The study focuses on measuring nitrous oxide isotopocules using isotope ratio mass spectrometry (IRMS) and addresses the need for a software tool to correct for ion source "scrambling."
  • A new Python package named pyisotopomer was developed to help researchers obtain specific coefficients for this correction and accurately analyze N2O samples.
  • Results indicate that calibration with reference materials is crucial and that IRMS scrambling can change over time, requiring regular recalibration and collaboration between laboratories for accurate measurements.
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Seabed hydrocarbon seeps present natural laboratories for investigating responses of marine ecosystems to petroleum input. A hydrocarbon seep near Scott Inlet, Baffin Bay, was visited for in situ observations and sampling in the summer of 2018. Video evidence of an active hydrocarbon seep was confirmed by methane and hydrocarbon analysis of the overlying water column, which is 260 m at this site.

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The spatiotemporal dynamics of denitrification in groundwater are still not well-understood because of a lack of efficient methods to quantify this biogeochemical reaction pathway. Previous research used the ratio of N to argon (Ar) to quantify net production of N via denitrification by separating the biologically generated N component from the atmospheric-generated components. However, this method does not allow the quantification of the atmospheric components accurately because the differences in gas partitioning between N and Ar are being neglected.

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Noble gases dissolved in natural waters are useful tracers for quantifying physical processes. Here, we describe a field-deployable gas equilibration mass spectrometer (GEMS) that provides continuous, real-time measurements of Ne, Ar, Kr, and Xe mole ratios in natural waters. Gas is equilibrated with a membrane contactor cartridge and measured with a quadrupole mass spectrometer, after in-line purification with reactive metal alloy getters.

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