In recent times, tremendous efforts have been devoted to the efficient and cost-effective advancements of electrochemically active metal oxide nanomaterials. Here, we have synthesized a facile nanomaterial of ZnO@PdO/Pd by employing extracted fuel from leaves following a hydrothermal route. The phyto-fueled ZnO@PdO/Pd nanomaterial was fabricated into a supercapacitor electrode and was scrutinized by galvanostatic charge-discharge, electrochemical impedance spectroscopy and cyclic voltammetry to evaluate its energy storage potential, and transport of electrons and conductivity.
View Article and Find Full Text PDFA modified co-precipitation method has been used for the synthesis of a PdO-2MnO nanocomposite as an efficient electrode material for the electro-catalytic oxygen evolution (OER) and hydrogen evolution reaction (HER). Palladium acetate and manganese acetate in molar ratio 1 : 4 were dissolved in water, and 10 ml of an aqueous solution of phyto-compounds was slowly added until completion of precipitation. The filtered and dried precipitates were then calcined at 450 °C to obtain a blackish brown colored mixture of PdO-2MnO nanocomposite.
View Article and Find Full Text PDFThe phytosynthesis of metal oxides nanoparticles (NPs) has been extensively reported; yet mechanism involved and incorporated bioactive compounds in the synthesized NPs are still need to be investigated. In this regard, here an efficient sustainable co-precipitation synthesis of zinc oxide nanoparticles (ZnO NPs) has been developed, employing hydrothermal reactions, using organic compounds of leaves. Pure hexagonal wurtzite ZnO was identified by X-ray diffraction and NPs in the size range of 50-60 nm were observed by field emission scanning electron microscopy.
View Article and Find Full Text PDFTo deal with fossil fuel depletion and the rise in global temperatures caused by fossil fuels, cheap and abundant materials are required, in order to fulfill energy demand by developing high-performance fuel cells and electrocatalysts. In this work, a natural organic agent has been used to synthesize nano-structured ZnO/MnO with high surface area and enhanced electrocatalytic performance. Upon pre-annealing treatment, mixed metal oxide precipitates are formed due to the complex formation between a metal oxide and organic extract.
View Article and Find Full Text PDFNickel sulfide is regarded as a material with tremendous potential for energy storage and conversion applications. However, it exists in a variety of stable compositions and obtaining a pure phase is a challenge. This study demonstrates a potentially scalable, solvent free and phase selective synthesis of uncapped α-NiS, β-NiS and α-β-NiS composites using nickel alkyl (ethyl, octyl) xanthate precursors.
View Article and Find Full Text PDFTransitional metal oxide nanomaterials are considered to be potential electrode materials for supercapacitors. Therefore, in the past few decades, huge efforts have been devoted towards the sustainable synthesis of metal oxide nanomaterials. Herein, we report a synergistic approach to synthesize spherical-shaped CoMoO electrode materials using an inorganic-organic template the hydrothermal route.
View Article and Find Full Text PDFIn search of affordable, flexible, lightweight, efficient and stable supercapacitors, metal oxides have been shown to provide high charge storage capacity but with poor cyclic stability due to structural damage occurring during the redox process. Here, we develop an efficient flexible supercapacitor obtained by carbonizing abundantly available and recyclable jute. The active material was synthesized from jute by a facile hydrothermal method and its electrochemical performance was further enhanced by chemical activation.
View Article and Find Full Text PDFHigh performance carbonized bamboo fibers were synthesized for a wide range of temperature dependent energy storage applications. The structural and electrochemical properties of the carbonized bamboo fibers were studied for flexible supercapacitor applications. The galvanostatic charge-discharge studies on carbonized fibers exhibited specific capacity of ~510F/g at 0.
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