Choosing the right precursor for thermal decomposition solution-phase synthesis of iron nanoparticles: tunable dissociation energies of ferrocene derivatives.

Organometallic coordination compounds in general and metallocenes in particular are convenient precursors for the synthesis of metal nanoparticles through thermal decomposition. The strength of the interaction between the metal ion and its ligands determines the conditions under which decomposition occurs, most importantly the range of temperatures and pressures at which a given compound is useful as a precursor. We show that a comprehensive analysis of all individual contributions to the ligand metal interactions that establishes the nature of the interaction can be used to select compounds that are tuned to a specific dissociation energy with advantageous properties under experimental conditions.