Highly Strained Polymeric Monolayer Stacked for Wafer-Scale and Transferable Nanodielectrics.

As the keystones of molecular electronics, high-quality nanodielectric layers are challenging to assemble due to the strictest criteria for their reliability and uniformity over a large area. Here, we report a strained poly(4-vinylphenol) monolayer, ready to be stacked to form defect-free wafer-scale nanodielectrics. The thickness of the nanodielectrics can be precisely adjusted in integral multiples of the 1.

Supramolecular Electronics: Monolayer Assembly of Nonamphiphilic Molecules via Water Surface-Assisted Molecular Deposition.

Utilizing softly confined self-assembly at the water surface represents a promising approach for the fabrication of two-dimensional molecular monolayers (2D MMs), which have predominantly been concentrated on amphiphilic organic compounds before. Herein, we introduce a straightforward method termed "water surface-assisted molecular deposition (WSAMD)" to organize nonamphiphilic molecules into dense monolayers with high reproducibility. To underscore the versatility and merit of this methodology in the field of supramolecular electronics, we have successfully fabricated a range of defect-free, uniform semiconducting polymer monolayers, featuring a thickness reflective of molecular architectures.

A Flexible, High-Voltage (>100 V) Generating Device Based on Zebra-Like Asymmetrical Photovoltaic Cascade.

The mutual conversion between light and electricity lies at the heart of optoelectronic and photonic applications. Maximization of the photoelectric conversion is a long-term goal that can be pursued via the fabrication of devices with ad-hoc architectures. In this framework, it is of utter importance to harvest and transform light irradiation into high electric potential in specific area for driving functional dielectrics that respond to pure electric field.

Construction of Laterally Asymmetric Heterojunctions with Sub-Micrometer Resolution by Hierarchical Self-Assembly of Polythiophene Nanofibers.

Polymeric semiconductors are crucial candidates for the construction of next-generation flexible and printable electronic devices. By virtue of the successful preparation of monodispersed colloidal solution in orthogonal solvent, poly(3-hexylthiophene) (P3HT) nanofibers are developed into versatile building blocks for nanoelectronics and their compatibilities are verified with photolithographic lift-off technology. Then, the joint efforts from both the bottom-up hierarchical self-assembly and top-down self-alignment technology have led to the realization of lateral asymmetric heterojunctions with resolution better than 1 µm.

Facile Synthesis of Water-Stable Multicolor Carbonized Polymer Dots from a Single Unconjugated Glucose for Engineering White Light-Emitting Diodes with a High Color Rendering Index.

Tunable emission carbonized polymer dots (CPDs) are highly desirable for the preparation of optoelectronic devices, especially white light-emitting diodes (WLEDs). In most available studies, polychromatic CPDs are synthesized using aromatic molecules as precursors. However, few studies report the successful synthesis of polychromatic CPDs using two or more unconjugated precursors.