Integrating UPLC-QTOF-MS/MS and UPLC-DAD to evaluate the influence of sulfur-fumigated Paeoniae Radix Alba on the overall quality of three Si-Wu-Tang formulations.

Introduction: Sulfur-fumigation of Paeoniae Radix Alba (PRA) could induce the chemical transformation of its bioactive component paeoniflorin into a sulfur-containing derivative paeoniflorin sulfite, and thus alter the quality, bioactivities, pharmacokinetics, and toxicities of PRA. However, how sulfur-fumigated PRA (S-PRA) affects the quality of PRA-containing complex preparations has not been intensively evaluated.

Objectives: We intend to evaluate the influence of S-PRA on the overall quality of three kinds of Si-Wu-Tang (SWT) formulations, i.

Preparation of surface molecular imprinting fluorescent sensor based on magnetic porous silica for sensitive and selective determination of catechol.

A magnetic fluorescent molecularly imprinted sensor was successfully prepared and implemented to determine catechol (CT). FeO nanoparticles were synthesized by the solvothermal technique and mesoporous FeO@SiO@mSiO imprinted carriers were prepared by coating nonporous and mesoporous SiO shells on the surface of the FeO subsequently. The magnetic surface molecularly imprinted fluorescent sensor was created after the magnetic mesoporous carriers were modified with γ-methacryloxyl propyl trimethoxy silane to introduce double bonds on the surface of the carries and the polymerization was carried out in the presence of CT and fluorescent monomers.

Preparation of molecularly imprinted ratiometric fluorescence sensor for visual detection of tetrabromobisphenol A in water samples.

A sensitive molecularly imprinted ratiometric fluorescence sensor was constructed for the first time to visually detect tetrabromobisphenol A (TBBPA). The blue fluorescent carbon quantum dots (CQDs) were coated with SiO through the reverse microemulsion method to obtain a stable internal reference signal CQDs@SiO. The ratiometric fluorescence sensor was finally prepared using red fluorescent CdTe QDs as the response signal in the presence of CQDs@SiO.

Quality consistency evaluation of commercial Prunellae Spica by integrating determination of secondary metabolites and saccharides.

Introduction: Prunellae Spica (PS) is a commonly used medicinal herb in China. Secondary metabolites and saccharides are major bioactive components of PS. However, holistic quality consistency of commercial PS is ambiguous due to lack of comprehensive evaluation methods and reliable quality control markers.

Effect of air and exhaust gas dilutions on ultra-fine particulate emissions in different combustion modes.

The effect of air and exhaust dilution ratios on the characteristics of ultra-fine particulate matter (PM) and combustion process in different combustion modes at low loads were investigated based on experimental and numerical simulation in this study. The combustion modes included partially premixed compression ignition (PPCI), diffusion combustion (DC), and modulated kinetics combustion (MKC). The air and exhaust gas dilution ratio varied from 0 % to 40 % and 0 % to 55 % respectively.