A dual-template synergistic assembly strategy towards the synthesis of extra-small nitrogen-doped mesoporous carbon nanospheres with large pores.

Functional mesoporous carbon nanomaterials with large pores and small particle sizes have broad accessibility, but remain challenging to achieve. This study proposed a dual-template synergistic assembly strategy to facilely synthesize extra-small nitrogen-doped mesoporous carbon nanospheres with large pores in a low-cost manner. Directed by the synergistic effect of the combination of surfactants, sodium oleate (anionic surfactant) and triblock copolymer-P123 (nonionic surfactant) were selected as templates to construct nanomicelles (nanoemulsions), which were co-assembled with melamine-based oligomers to form composite nanomicelles, thus obtaining nitrogen-doped mesoporous polymer nanospheres (NMePS) and then nitrogen-doped mesoporous carbon nanospheres (NMeCS).

Anisotropic hat-like carbon nanoparticles with tunable inner hollow architectures by growth and dissolution kinetics control.

The synthesis of nanoparticles with a hollow and anisotropic structure have attracted considerable interest in synthetic methodology and diverse potential applications, but endowing them with delicate control of the hollow structure and outer anisotropic morphology remains a significant challenge. In this study, anisotropic nanoparticles with hat-like morphology are prepared via a kinetics-controlled growth and dissolution strategy. Starting from forming solid polymer nanospheres with location-specific compositional chemistry distribution based on the distinct reactivity and growth kinetics of two reactants.

Bioinspired Hierarchical Nanofabric Electrode for Silicon Hydrovoltaic Device with Record Power Output.

Direct electricity generation from water flow/evaporation, coined hydrovoltaic effect, has recently attracted intense interest as a facile approach to harvest green energy from ubiquitous capillary water flow or evaporation. However, the current hydrovoltaic device is inferior in output power efficiency compared to other renewable energy devices. Slow water evaporation rate and inefficient charge collection at device electrodes are two fundamental drawbacks limiting energy output efficiency.

Facile Preparation of Porous Carbon Derived from Industrial Biomass Waste as an Efficient CO Adsorbent.

A porous carbon CO adsorbent based on soybean cake (industrial biomass waste) has been successfully prepared by direct carbonation, following KOH activation. The prepared porous carbon adsorbent exhibits efficient CO capture performance with the highest adsorption capacity of 4.19 and 6.