When couples fight about money, what do they fight about?

Conflicts about money and finances can be destructive for both the quality and longevity of relationships. This paper reports on a descriptive analysis of the contents of financial conflicts in two samples. Study 1 examined severe financial conflicts in social media posts ( = 1014) from ().

Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies.

The heterogeneous solid-gas reactions of crystals of [Rh(L)(propene)][BAr] (, L = BuPCHCHPBu) with H and propene, 1-butene, propyne, or 1-butyne are explored by gas-phase nuclear magnetic resonance (NMR) spectroscopy under batch conditions at 25 °C. The temporal evolution of the resulting parahydrogen-induced polarization (PHIP) effects measures catalytic flux and thus interrogates the efficiency of catalytic pairwise -H transfer, speciation changes in the crystalline catalyst at the molecular level, and allows for high-quality single-scan H, C NMR gas-phase spectra for the products to be obtained, as well as 2D-measurements. Complex reacts with H to form dimeric [Rh(L)(H)(μ-H)][BAr] (), as probed using EXAFS; meanwhile, a single-crystal of equilibrates NMR silent -H with its NMR active ortho isomer, contemporaneously converting into , and and each convert -H into -H at different rates.

Plasmacytoid dendritic cells have divergent effects on HIV infection of initial target cells and induce a pro-retention phenotype.

Although HIV infection inhibits interferon responses in its target cells in vitro, interferon signatures can be detected in vivo soon after sexual transmission, mainly attributed to plasmacytoid dendritic cells (pDCs). In this study, we examined the physiological contributions of pDCs to early HIV acquisition using coculture models of pDCs with myeloid DCs, macrophages and the resting central, transitional and effector memory CD4 T cell subsets. pDCs impacted infection in a cell-specific manner.

η-Alkene Complexes of [Rh(PONOP-Pr)(L)] Cations (L = COD, NBD, Ethene). Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-Pr)(η-H)].

Rhodium-alkene complexes of the pincer ligand κ-CHN-2,6-(OPPr) (PONOP-Pr) have been prepared and structurally characterized: [Rh(PONOP-Pr)(η-alkene)][BAr] [alkene = cyclooctadiene (COD), norbornadiene (NBD), ethene; Ar = 3,5-(CF)CH]. Only one of these, alkene = COD, undergoes a reaction with H (1 bar), to form [Rh(PONOP-Pr)(η-COE)][BAr] (COE = cyclooctene), while the others show no significant reactivity. This COE complex does not undergo further hydrogenation.