Harnessing the Potential of Amide-Linked Gemini Surfactants for Corrosion Inhibition and Antimicrobial Activity: From Molecular Design to Functional Performance.

Gemini surfactants, also called Gemini, especially those with quaternary ammonium head groups, are recognized for their distinctive aggregation behavior and enhanced structure-activity relationships. The unique dual-head and dual-tail structure of Gemini grants them superior surface activity, allowing them to effectively lower surface and interfacial tension. To investigate the self-assembly behavior and surface-active properties that make them suitable as anticorrosion and antimicrobial agents, a series of cationic Gemini featuring amide bonds and varying alkyl chain lengths were synthesized.

Branch retinal vein occlusion and Valsalva manoeuvre in wind instrument players and singers.

Clinical Relevance: There are many recognised risk factors for retinal vein occlusions. It is plausible that musicians who play wind instruments or use their voice as their primary instrument may be at increased risk of branch retinal vein occlusions through repeated Valsalva manoeuvre.

Background: Repeated valsalva manoeuvres are commonly performed by musicians using high resistance wind instruments.

Cyano-Bridged Bimetallic Polymer Network-Derived PdFe Intermetallic for Aqueous Rechargeable Zinc-Air Batteries.

The rational design and synthesis of bifunctionally active and durable oxygen electrocatalysts have garnered significant attention for electrochemical energy conversion and storage. Intermetallic nanostructures are particularly promising for these applications due to their unique catalytic properties and exceptional durability. In this study, we present a fascinating synthetic approach for the direct synthesis of a bifunctional oxygen electrocatalyst based on nitrogen-doped carbon-encapsulated ordered PdFe (o-PdFe@NC) intermetallic, using a cyano-bridged bimetallic single-source precursor tailored for aqueous rechargeable zinc-air batteries (ZABs).