Surface oxidation of single wall carbon nanohorns for the production of surfactant free water-based colloids.

In this work, powders of Single Wall Carbon Nanohorns (SWCNHs), a typical hydrophobic material, were oxidized with concentrated HNO with the aim of surface carboxylation and consequent improved hydrophilicity and dispersibility in polar solvents. Dynamic Light Scattering and ζ-potential measurements demonstrated that very stable colloidal suspensions of SWCNH in water were obtained in total absence of stabilizers. By properly optimizing the reaction parameters, the suspensions achieved stability even higher than colloids with similar composition but prepared with the use of surfactants.

Tuning the thermal diffusivity of silver based nanofluids by controlling nanoparticle aggregation.

With the aim of preparing stable nanofluids for heat exchange applications and to study the effect of surfactant on the aggregation of nanoparticles and thermal diffusivity, stable silver colloids were synthesized in water by a green method, reducing AgNO₃ with fructose in the presence of poly-vinylpyrollidone (PVP) of various molecular weights. A silver nanopowder was precipitated from the colloids and re-dispersed at 4 vol% in deionized water. The Ag colloids were characterized by UV-visible spectroscopy, combined dynamic light scattering and ζ-potential measurements, and laser flash thermal diffusivity.

Absorption and scattering properties of carbon nanohorn-based nanofluids for direct sunlight absorbers.

In the present work, we investigated the scattering and spectrally resolved absorption properties of nanofluids consisting in aqueous and glycol suspensions of single-wall carbon nanohorns. The characteristics of these nanofluids were evaluated in view of their use as sunlight absorber fluids in a solar device. The observed nanoparticle-induced differences in optical properties appeared promising, leading to a considerably higher sunlight absorption with respect to the pure base fluids.

Carbon nanohorns-based nanofluids as direct sunlight absorbers.

The optimization of the poor heat transfer characteristics of fluids conventionally employed in solar devices are at present one of the main topics for system efficiency and compactness. In the present work we investigated the optical and thermal properties of nanofluids consisting in aqueous suspensions of single wall carbon nanohorns. The characteristics of these nanofluids were evaluated in view of their use as sunlight absorber fluids in a solar device.

In situ window cleaning by laser blowoff through optical fiber.

The feasibility of a window cleaning system based on the laser blowoff technique is investigated to remove the impurity deposition on vacuum windows of the modified reversed field experiment fusion device. The laser pulse is sent to the window through a fused silica fiber optic (phi=1 mm), then focused on its internal surface, single shot ablating up to approximately 5 mm(2) of the impurity layer; the focused pulse is scanned across the window to clean its entire surface. The composition of the deposited layer is studied through the secondary ion mass spectrometry and profilometry techniques.