Ruthenium-catalyzed hydroarylation reactions as the strategy towards the synthesis of alkylated arenes and substituted alkenes.

Metal-catalyzed hydroarylation reactions are always powerful tools in organic synthesis since they can form C-C or C-heteroatom bonds in an atom and step economic manner. Medicinally and biologically relevant scaffolds can be easily and efficiently synthesized using this strategy. By tuning the directing groups that are present on the arenes, regioselectivity can be induced to the C-H activation.

Applications of iron pincer complexes in hydrosilylation reactions.

Due to its abundance, low cost and low toxicity, the first-row transition metal, iron is widely preferred as a catalyst in organic synthesis. The only drawback of lower selectivity due to high reactivity and low stability of the metal centre is tuned by using pincer ligands of different types. The different iron pincer complexes thus prepared are extensively used in catalyzing different types of organic reactions with great selectivity and functional group tolerance under moderate reaction conditions.

Recent advances and prospects in the Zn-catalysed Mannich reaction.

Zn-catalysed reactions are ubiquitously important due to their inexpensive, generally less toxic and atom-economic nature. According to the modern criteria of sustainability, their use in a catalytic manner is a highly desirable goal, especially when using chiral ligands. Considering the relevance of well-established zinc-mediated C-C bond formation reactions, it is relatively surprising that the use of Zn as a catalyst is still underdeveloped, especially in comparison with other transition metals.

Recent advances and perspectives in ruthenium-catalyzed cyanation reactions.

The cyanation reaction has achieved rapid progress in recent times. The ability to exhibit multiple oxidation states increased the demand of ruthenium in the field of catalysis. These cyanation reactions have wide application in pharmacological and biological fields.

Progress and prospects in copper-catalyzed C-H functionalization.

Copper-catalyzed C-H functionalization is becoming a significant area in organic chemistry. Copper is now widely used as a catalyst in organic synthesis as it is inexpensive and not very toxic. Functionalization of C-H bonds to construct wide varieties of organic compounds has received much attention in recent times.