Intrinsically Conductive and Cu-Functionalized Polymer-Composite Membranes as Gas Diffusion Electrodes for CO Electroreduction.

We introduced a new class of gas diffusion electrodes (GDEs) with adjustable pore morphology. We fabricated intrinsically conductive polymer-composite membranes containing carbon filler, enabling a pore structure variation through film casting cum phase separation protocols. We further selectively functionalized specific pore regions of the membranes with Cu by a NaBH-facilitated coating strategy.

Gas Diffusion Electrodes for Electrocatalytic Oxidation of Gaseous Ammonia: Stepping Over the Nitrogen Energy Canyon.

As ammonia continues to gain more and more interest as a promising hydrogen carrier compound, so does the electrochemical ammonia oxidation reaction (AmOR). To avoid the liberation of H in a reverse Haber-Bosch reaction under release of the energetically more favorable N, we propose the oxidation of ammonia to value-added nitrite (NO ), which is usually obtained during the Ostwald process. We investigated the anodic oxidation of gaseous ammonia directly supplied to a gas diffusion electrode (GDE) using a variety of compositionally different multi-metal catalysts coated on Ni foam under the simultaneous formation of H at the cathode.

Tunable Syngas Formation at Industrially Relevant Current Densities via CO Electroreduction and Hydrogen Evolution over Ni and Fe-derived Catalysts obtained via One-Step Pyrolysis of Polybenzoxazine Based Composites.

Simultaneous electroreduction of CO and HO to syngas can provide a sustainable feed for established processes used to synthesize carbon-based chemicals. The synthesis of MO/M-N-Cs (M = Ni, Fe) electrocatalysts reported via one-step pyrolysis that shows increased performance during syngas electrosynthesis at high current densities with adaptable H/CO ratios, e.g.

Accelerating CO electrochemical conversion towards industrial implementation.

The electrochemical conversion of carbon dioxide by means of renewable electricity holds great promise. However, despite significant progress in current literature, there remains a significant gap between fundamental research and the industrial demands to establish new disruptive technologies in real world applications. This gap primarily arises from a mismatch between performance parameters and requirements in both areas, leading to significant challenges in technology transfer.