A road map to assess critical materials content in boron industrial wastes using sustainable micro-X-ray fluorescence and total reflection X-ray fluorescence instrumentation.

Turkey is the leading country in the world in terms of boron production and sale. Increasing boron production goes along with an increasing generation of boron wastes. The pollution of the soil and the air around the waste piles, as well as the occupation of several square kilometers of ground, are major environmental problems.

Detailed Characterization of the Surface and Growth Mechanism of Monodisperse NiSn Nanoparticles.

Synthesis of most tin-based bimetallic nanoparticles is a challenging task because of the differences in the redox potential and the melting point between both components. This article presents a co-reduction synthesis of monoclinic NiSn nanoparticles. Varying time and temperature gives the possibility to control the size of the nanoparticles in the range of 4-12 nm.

Converting bimetallic M (M = Ni, Co, or Fe)-Sn nanoparticles into phosphides: a general strategy for the synthesis of ternary metal phosphide nanocrystals.

Ternary metal tin phosphides are promising candidates for electrochemical or catalytic applications. Nevertheless, their synthesis, neither as bulk nor nanomaterials is well investigated in the literature. Here, we describe a general synthetic strategy to convert bimetallic M-Sn (M = Ni, Co, and Fe) nanoparticles to ternary metal phosphides by decomposition of tributylphosphine at 300 °C.

Pre-/post-functionalization in dipyrrin metal complexes - antitumor and antibacterial activity of their glycosylated derivatives.

A post-functionalization route to tris(dipyrrinato) metal complexes is presented giving access to a range of new complexes relevant in the context of medicinal inorganic chemistry. A pentafluorophenyl group in the meso-position of the dipyrrin ligand serves as an anchor for the connection with alcohols and thiocarbohydrates. The photochemotherapeutic activity of the complexes has been assessed in cellular assays with tumor cell lines and against the Gram-positive bacterium S.

Nucleophilic Aromatic Substitution on Pentafluorophenyl-Substituted Dipyrranes and Tetrapyrroles as a Route to Multifunctionalized Chromophores for Potential Application in Photodynamic Therapy.

The application of porphyrinoids in biomedical fields, such as photodynamic therapy (PDT), requires the introduction of functional groups to tune their solubility for the biological environment and to allow a coupling to other active moieties or carrier systems. A valuable motif in this regard is the pentafluorophenyl (PFP) substituent, which can easily undergo a regiospecific nucleophilic replacement (S Ar) of its para-fluorine atom by a number of nucleophiles. Here, it is shown that, instead of amino-substitution on the final porphyrinoid or BODIPY (boron dipyrromethene), the precursor 5-(PFP)-dipyrrane can be modified with amines (or alcohols).