Evidence through Thermal Analysis of Retro Diels-Alder Reaction in Model Networks Based on Anthracene Modified Polyester Resins.

The present work is focused on polyester resins obtained from the diglycidyl ether of bisphenol A and anthracene modified 5-maleimidoisophthalic acid. Because the maleimide-anthracene Diels-Alder (DA) adduct is stable at high temperatures, it is considered a good option for high performance polymers. However, the information related to the retroDA reaction for this type of adduct is sometimes incoherent.

Novel Bio-Based Materials: From Castor Oil to Epoxy Resins for Engineering Applications.

The paper presents the synthesis and thermal behavior of novel epoxy resins prepared from epoxidized castor oil in the presence of or without trimethylolpropane triglycidyl ether (TMP) crosslinked with 3-hexahydro-4-methylphtalic anhydride (MHHPA) and their comparison with a petroleum-based epoxy resin (MHHPA and TMP). Epoxidized castor oil (ECO) was obtained via in situ epoxidation of castor oil with peroxyacetic acid. The chemical structures of castor oil (CO), ECO, and epoxy matrix were confirmed using FT-IR and H-NMR spectroscopy.

Genetic polymorphism of gene in Sumba Ongole () cattle and its association with growth traits.

Objective: As one of the most valuable genetic resources of Ongole beef cattle globally, the Sumba Ongole (SO) cattle population is being studied in this investigation of myostatin () gene polymorphism and its association with growth traits.

Materials And Methods: Blood samples from 161 SO cattle were collected and analyzed. Deoxyribonucleic acid (DNA) was isolated.

MWCNTs Composites-Based on New Chemically Modified Polysulfone Matrix for Biomedical Applications.

Polyvinyl alcohol (PVA) is a non-toxic biosynthetic polymer. Due to the hydrophilic properties of the PVA, its utilization is an easy tool to modify the properties of materials inducing increased hydrophilicity, which can be noticed in the surface properties of the materials, such as wettability. Based on this motivation, we proposed to obtain high-performance composite materials by a facile synthetic method that involves the cross-linking process of polyvinyl alcohol (PVA) with and aldehyde-functionalized polysulfone(mPSF) precursor, prior to incorporation of modified MWCNTs with hydrophilic groups, thus ensuring a high compatibility between the polymeric and the filler components.

Climate transition at the Eocene-Oligocene influenced by bathymetric changes to the Atlantic-Arctic oceanic gateways.

The Eocene–Oligocene Transition (∼33.9 Ma) marks the largest step transformation within the Cenozoic cooling trend and is characterized by a sudden growth of the Antarctic ice sheets, cooling of the interior ocean, and the establishment of strong meridional temperature gradients. Here we examine the climatic impact of oceanic gateway changes at the Eocene–Oligocene Transition by implementing detailed paleogeographic reconstructions with realistic paleobathymetric models for the Atlantic–Arctic basins in a state-of-the-art earth system model (the Norwegian Earth System Model [NorESM-F]).