In this study, we performed the physicochemical and electrochemical characterization of a decorated macrocyclic aluminium(iii) phthalocyanine complex (AlTMQNCAPc). Subsequently, the AlTMQNCAPc@MWCNT/GC electrode was used for the electrochemical detection of glucose and hydrogen peroxide (HO) by cyclic voltammetry (CV), differential pulse voltammetry (DPV), and chronoamperometry (CA). Moreover, the limit of detection, linear range, and sensitivity for glucose and HO were investigated (CV: 2.
View Article and Find Full Text PDFAn endo-poly-galacturonase (PGU1) gene product is responsible for the pectolytic activity in Saccharomyces bayanus. Therefore, it is of interest to document the comparative structural and functional analysis of the PGU1 protein from Saccharomyces bayanus with those in other Saccharomyces related species. The molecular docking analyses of pectin with the different homology models of PGU1 protein from several Saccharomyces species are reported.
View Article and Find Full Text PDFNucleosides Nucleotides Nucleic Acids
September 2022
A series of metal(II) complexes (=Co (II), Ni(II) and Cu(II)) supported by Schiff base ligand (=()-'-((6-hydroxybenzo[]oxazol-5-yl)methylene)isonicotinohydrazide) has been designed and developed from condensation of 6-hydroxybenzo[]oxazole-5-carbaldehyde and isoniazid. The ligand (HL) and its metal(II) complexes were structurally characterized utilizing a variety of physicochemical and spectroscopic approaches. The study shows that Schiff bases (HL) act as monobasic tridentate ONO ligand and conform to octahedral geometry according to the general formula [M(HL)].
View Article and Find Full Text PDFA novel tetra-4-{()-[(8-aminonaphthalen-1-yl)imino]methyl}-2-methoxyphenol Co(ii) phthalocyanine (CoTANImMMPPc) was synthesized using a precursor protocol and characterized electroanalytical and spectroscopic techniques. The FT-IR spectra of the synthesized compounds showed significant peaks corresponding to the functional groups of the precursors and phthalocyanine (Pc) compound. The mass and NMR spectra confirmed the formation of the target precursor compounds.
View Article and Find Full Text PDFThe progress made by the scientific community in emerging photovoltaic technologies over the past two decades has been outstanding. Numerous methods have been developed for the preparation of hybrid organic-inorganic perovskite solar cells. The power conversion efficiency has been up to 14% by a one-step vacuum deposition technique.
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