Alloxazine and ferrocyanide are suggested as the redox couple for an aqueous organic redox flow battery (AORFB). Alloxazine is further modified by carboxylic acid (COOH) groups (alloxazine-COOH) to increase the aqueous solubility and to pursue a desirable shift in the redox potential. For obtaining a better AORFB performance, the overall redox reactivity of AORFB should be improved by the enhancement of the rate-determining reaction of the redox couple.
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