Zinc speciation in fly ash from MSWI using XAS - novel insights and implications.

The chemical forms of zinc in fly ash from municipal solid waste incineration (MSWI) crucially affect ash management, influencing both material recovery options and the risk of unwanted leaching into ecosystems. The zinc speciation was investigated in fly ash samples sourced from full-scale MSWI plants, including four grate fired boilers (GB) and one fluidized bed boiler (FB). We applied X-ray Absorption Spectroscopy (XAS), and the spectra were analyzed against a unique library of over 30 relevant compounds, tailored to the nuances of zinc chemistry of fly ash.

Resource Recovery of Spent Lithium-Ion Battery Cathode Materials by a Supercritical Carbon Dioxide System.

The increasing global market size of high-energy storage devices due to the boom in electric vehicles and portable electronics has caused the battery industry to produce a lot of waste lithium-ion batteries. The liberation and de-agglomeration of cathode material are the necessary procedures to improve the recycling derived from spent lithium-ion batteries, as well as enabling the direct recycling pathway. In this study, the supercritical (SC) CO was innovatively adapted to enable the recycling of spent lithium-ion batteries (LIBs) based on facilitating the interaction with a binder and dimethyl sulfoxide (DMSO) co-solvent.

Disordered Crystal Structure and Anomalously High Solubility of Radium Carbonate.

Radium-226 carbonate was synthesized from radium-barium sulfate (RaBaSO) at room temperature and characterized by X-ray powder diffraction (XRPD) and extended X-ray absorption fine structure (EXAFS) techniques. XRPD revealed that fractional crystallization occurred and that two phases were formed─the major Ra-rich phase, Ra(Ba)CO, and a minor Ba-rich phase, Ba(Ra)CO, crystallizing in the orthorhombic space group (no. 62) that is isostructural with witherite (BaCO) but with slightly larger unit cell dimensions.

Recovery of critical metals from EV batteries via thermal treatment and leaching with sulphuric acid at ambient temperature.

In the upcoming years, todaýs e-mobility will challenge the capacity of sustainable recycling. Due to the presence of organic components (electrolyte, separator, casings, etc.), future recycling technologies will combine thermal pre-treatment followed by hydrometallurgical processing.

Hydrometallurgical recycling of EV lithium-ion batteries: Effects of incineration on the leaching efficiency of metals using sulfuric acid.

The growing demand for lithium-ion batteries will result in an increasing flow of spent batteries, which must be recycled to prevent environmental and health problems, while helping to mitigate the raw materials dependence and risks of shortage and promoting a circular economy. Combining pyrometallurgical and hydrometallurgical recycling approaches has been the focus of recent studies, since it can bring many advantages. In this work, the effects of incineration on the leaching efficiency of metals from EV LIBs were evaluated.

Incineration of EV Lithium-ion batteries as a pretreatment for recycling - Determination of the potential formation of hazardous by-products and effects on metal compounds.

In several industrial Lithium-ion batteries recycling processes, a thermal treatment with oxidative atmosphere is used to separate the battery components and to remove the organic components. This method is often combined with hydrometallurgical processes with the aim to increase the metal recovery rate or to improve the efficiency of the existing processes. Despite such efforts, the effects of a thermal treatment in an oxidative atmosphere on the microstructure and composition on cathode and anode materials has not been explored.

Novel process for decontamination and additional valorization of steel making dust processing using two-step correlative leaching.

Recycling of steel making dusts often targets Zn removal. Other heavy metals such as Mo, W or Cr do not receive as much attention, and the decontamination of the dusts from these constituents is scarcely addressed in the literature. This study presents a novel approach of the selective separation of Mo from steel making dusts using alkaline solutions with low concentrations, before Zn removal using concentrated alkaline medium.

Recovery of industrial valuable metals from household battery waste.

The modern community is dependent on electronic devices such as remote controls, alarm clocks, electric shavers, phones and computers, all of which are powered by household batteries. Alkaline, zinc-carbon (Zn-C), nickel metal hydride, lithium and lithium-ion batteries are the most common types of household energy storage technologies in the primary and secondary battery markets. Primary batteries, especially alkaline and Zn-C batteries, are the main constituents of the collected spent battery stream due to their short lifetimes.

Selective recovery of cobalt from the secondary streams after NiMH batteries processing using Cyanex 301.

Cobalt is considered to be a critical raw material for the European Union. Since it has limited supply, substantial efforts should be made to develop sustainable methods to recover cobalt from alternative sources. Hydrometallurgical processing of spent NiMH batteries generates a concentrated stream containing, preferably, Co (11.

Production of zinc and manganese oxide particles by pyrolysis of alkaline and Zn-C battery waste.

Production of zinc and manganese oxide particles from alkaline and zinc-carbon battery black mass was studied by a pyrolysis process at 850-950°C with various residence times under 1L/minN2(g) flow rate conditions without using any additive. The particular and chemical properties of the battery waste were characterized to investigate the possible reactions and effects on the properties of the reaction products. The thermodynamics of the pyrolysis process were studied using the HSC Chemistry 5.