Diffusiophoresis in Polymer and Nanoparticle Gradients.

Diffusiophoresis is the movement of the colloidal particles in response to a concentration gradient and can be observed for both electrolyte (e.g., salt) and nonelectrolyte (e.

Diffusiophoretic Behavior of Polyelectrolyte-Coated Particles.

Diffusiophoresis, the movement of particles under a solute concentration gradient, has practical implications in a number of applications, such as particle sorting, focusing, and sensing. For diffusiophoresis in an electrolyte solution, the particle velocity is described by the electrolyte relative concentration gradient and the diffusiophoretic mobility of the particle. The electrolyte concentration, which typically varies throughout the system in space and time, can also influence the zeta potential of particles in space and time.

Diffusiophoresis and Diffusio-osmosis into a Dead-End Channel: Role of the Concentration-Dependence of Zeta Potential.

Chemically induced transport methods open up new opportunities for colloidal transport in dead-end channel geometries. Diffusiophoresis, which describes particle movement under an electrolyte concentration gradient, has previously been demonstrated in dead-end channels. The presence of solute concentration gradients in such channels induces particle motion (phoresis) and fluid flow along solid walls (osmosis).

The associations between reading mind in the eyes abilities, alexithymia, empathy, and bullying behavior in Turkish adolescents.

Problem: The development of any program to reduce bullying is possible with a better understanding of the associated underlying factors with its emergence. This study, therefore, aimed to investigate three different social cognitive abilities: abilities to read minds in the eyes, alexithymic personality traits, and empathy, in association with bullying behaviors in adolescents. Although these factors have been studied separately, our data highlighted their effect, relationship, and interconnectivity.

Identification and sorting of particle chirality using liquid crystallinity.

Particles dispersed in liquid crystals (LCs) have been shown to assemble due to the elastic interactions arising from the molecular anisotropy. Studies have shown that the alignment of the particles within LCs were strongly dependent on the surface director of LCs on particles. Different from the past studies involving particles with degenerate planar anchoring of LCs, this study shows that the azimuthal surface director can be used to control and finely tune the positioning of the particles in LCs.

Design Parameters and Principles of Liquid-Crystal-Templated Synthesis of Polymeric Materials via Photolithography.

The design parameters and principles for the synthesis of polymeric microscopic objects using a method that combines photolithography and liquid crystal (LC) molecular templates have been demonstrated. Specifically, mixtures of a reactive mesogen (RM257) and nonreactive LC (E7) were polymerized using UV light and a photomask. We used photomasks with circular, triangular, rectangular, square, star-shaped, and heart-shaped features to provide initial shapes to the objects.

Liquid Crystal Templates Combined with Photolithography Enable Synthesis of Chiral Twisted Polymeric Microparticles.

Liquid crystals (LC), when combined with photolithography, enable synthesis of microparticles with 2D and 3D shapes and internal complexities. Films of nematic LCs are prepared using mixtures of reactive (RM257) and non-reactive mesogens with controlled alignment of LCs at the confining surfaces, photo-polymerized the RM257 using a photomask, and then extracted the unreacted mesogens to yield the polymeric microparticles. The extraction results in a controlled anisotropic shrinkage amount dependent on the RM257 content and the direction dependent on LC alignment.