Biological wood oxidation (BWO) is a composting heat recovery system tailored for woody lignocellulose valorization, with the potential to generate sustainable and low-temperature heat. This study investigated the effects of feedstock particle sizing and periodic nutrient supplementation (PNS) on microbial activity and wood decomposition during BWO. Birch wood was processed into sawdust (<5 mm) and cubes of various diameters (5, 10, and 15 mm), incubated in batch-mode BWO reactors for 88 days, and periodically supplemented with a nutrient medium.
View Article and Find Full Text PDFSulfidogenesis is a promising technology for the selective recovery of chalcophile bulk metals (e.g. Cu, Zn, and Co) from metal-contaminated waters such as acid mine drainage (AMD) and metallurgy waste streams.
View Article and Find Full Text PDFMicrobial electrolysis cells (MECs) have been proven effective for oxidizing ammonium (NH), where the anode acts as an electron acceptor, reducing the energy input by substituting oxygen (O). However, O has been proved to be essential for achieving high removal rates MECs. Thus, precise control of oxygen supply is crucial for optimizing treatment performance and minimizing energy consumption.
View Article and Find Full Text PDFBiological desulfurization under haloalkaline conditions has been applied worldwide to remove hydrogen sulfide (HS) from sour gas steams. The process relies on sulfide-oxidizing bacteria (SOB) to oxidize HS to elemental sulfur (S), which can then be recovered and reused. Recently, a dual-reactor biological desulfurization system was implemented where an anaerobic (sulfidic) bioreactor was incorporated as an addition to a micro-oxic bioreactor, allowing for higher S selectivity by limiting by-product formation.
View Article and Find Full Text PDFThe transition of the current fossil based chemical industry to a carbon-neutral industry can be done by the substitution of fossil carbon for defossilized carbon in the production of base chemicals. Methanol is one of the seven base chemicals, which could be used to produce other base chemicals (light olefins and aromatics). In this research, we evaluated the synthesis of methanol based on defossilized carbon sources (maize, waste biomass, direct air capture of CO (DAC), and CO from the cement industry) by considering carbon source availability, energy, water, and land demand.
View Article and Find Full Text PDFElectrochemically mediated struvite precipitation (EMSP) offers a robust, chemical-free process towards phosphate and ammonium reclamation from nutrients-rich wastewater, i.e., swine wastewater.
View Article and Find Full Text PDFRemoval of hydrogen sulfide (HS) can be achieved using the sustainable biological desulfurization process, where HS is converted to elemental sulfur using sulfide-oxidizing bacteria (SOB). A dual-bioreactor process was recently developed where an anaerobic (sulfidic) bioreactor was used between the absorber column and micro-oxic bioreactor. In the absorber column and sulfidic bioreactor, polysulfides (S) are formed due to the chemical equilibrium between HS and sulfur (S).
View Article and Find Full Text PDFBioelectrochemical systems (BESs) are considered to be energy-efficient to convert ammonium, which is present in wastewater. The application of BESs as a technology to treat wastewater on an industrial scale is hindered by the slow removal rate and lack of understanding of the underlying ammonium conversion pathways. This study shows ammonium oxidation rates up to 228 ± 0.
View Article and Find Full Text PDFSoil organic carbon (SOC) is essential for most soil functions. Changes in land use from natural land to cropland disrupt long-established SOC balances and reduce SOC levels. The intensive use of chemical fertilisers in modern agriculture accelerates the rate of SOC depletion.
View Article and Find Full Text PDFExtensive agricultural activities have been shown to degrade soils, promoting research into improving soil quality. One such method is to increase the amount of organic matter in the soil, and domestic organic residues (DOR) are commonly used for this purpose. The environmental impact of DOR-derived products, from production to agricultural application, remains unclear in current research.
View Article and Find Full Text PDFThe application of organic amendments (OAs) obtained from biological treatment technologies is a common agricultural practice to increase soil functionality and fertility. OAs and their respective pretreatment processes have been extensively studied. However, comparing the properties of OAs obtained from different pretreatment processes remains challenging.
View Article and Find Full Text PDFMetal sulfide precipitation is a viable technology for high-yield metal recovery from hydrometallurgical streams, with the potential to streamline the process design. A single-stage elemental sulfur (S)-reducing and metal sulfide precipitating process can optimize the operational and capital costs associated with this technology, boosting the competitiveness of this technology for wider industrial application. However, limited research is available on biological sulfur reduction at high temperature and low pH, frequent conditions of hydrometallurgical process waters.
View Article and Find Full Text PDFStimulated by the desire to achieve a Net Zero energy economy, the demand for renewable fuels is growing rapidly. The production of toxic waste streams that accompanies the transition from fossil fuels to renewable fuels is often overlooked. These waste streams include, among others, thiols and ammonia, and benzene, toluene, and xylene (BTX).
View Article and Find Full Text PDFPhosphorus (P) is often regarded as the primary stimulant for eutrophication, while its importance as a crucial life element is also well acknowledged. Given its future scarcity, P recycling from waste streams is suggested and practiced. Electrochemically mediated precipitation (EMP) is a robust and chemical-free process for P removal and recovery, yet it requires further developments.
View Article and Find Full Text PDFSulphide is a toxic and corrosive compound and requires removal from waste streams. Recent discoveries show that sulphide oxidising bacteria (SOB) from modern desulphurisation plants are able to spatially separate sulphide removal and oxygen reduction when exposed to intermittent anaerobic and aerobic environments. Here, SOB act as electron shuttles between electron donor and acceptor.
View Article and Find Full Text PDFFor over 30 years, biological gas desulfurization under halo-alkaline conditions has been studied and optimized. This technology is currently applied in already 270 commercial installations worldwide. Sulfur particle separation, however, remains a challenge; a fraction of sulfur particles is often too small for liquid-solid separation with conventional separation technology.
View Article and Find Full Text PDFDuring electrochemical nutrient recovery, current and ion exchange membranes (IEM) are used to extract an ionic species of interest (e.g., ion) from a mixture of multiple ions.
View Article and Find Full Text PDFToxic selenium oxyanions and sulfur species are often jointly present in contaminated waters and soils. This study investigated the effect on kinetics and resulting products for bio-reduction of selenium oxyanions in the presence of biologically produced sulfur resulting from bio-oxidation of sulfide in (bio)gas-desulfurization (bio-S) and of sulfate. Selenite and selenate (~2 mmol L) bio-reduction was studied in batch up to 28 days at 30 C and pH 7 using lactic acid and a sulfate-reducing sludge, 'Emmtec'.
View Article and Find Full Text PDFOrganic amendments (OAs) produced via composting, anaerobic digestion, or lactic acid fermentation, can be used to replenish soil carbon. Not all OAs production technologies preserve C and nutrients in the same way. In this study, we compared the influence of these technologies (i.
View Article and Find Full Text PDFSulfide oxidizing bacteria (SOB) are widely applied in industry to convert toxic HS into elemental sulfur. Haloalkaliphilic planktonic SOB can remove sulfide from solution under anaerobic conditions (SOB are 'charged'), and release electrons at an electrode (discharge of SOB). The effect of this electron shuttling on product formation and biomass growth is not known.
View Article and Find Full Text PDFPhosphorus (P) is an essential element for the growth and reproduction of organisms. Unfortunately, the natural P cycle has been broken by the overexploitation of P ores and the associated discharge of P into water bodies, which may trigger the eutrophication of water bodies in the short term and possible P shortage soon. Consequently, technologies emerged to recover P from wastewater to mitigate pollution and exploit secondary P resources.
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