Semi-transparent 3D microelectrodes buried in fused silica for photonics applications.

We report the realization of semi-transparent 3D microelectrodes fully embedded in a fused silica substrate by a combination of femtosecond laser microfabrication and inkjet printing. We also demonstrate the application of such electrodes in a proof-of-concept lab-on-chip device configuration, which acts as a liquid crystal molecular polarization rotator using on-chip electric fields. This work constitutes a first of its kind synergy between two widely used microfabrication techniques, femtosecond laser and inkjet, demonstrating a very efficient integration of optical, electrical and microfluidic components in a unique platform and thus enabling fast prototyping of 3D structured electro-optic lab-on-chips.

Macroscopic and high-throughput printing of aligned nanostructured polymer semiconductors for MHz large-area electronics.

High-mobility semiconducting polymers offer the opportunity to develop flexible and large-area electronics for several applications, including wearable, portable and distributed sensors, monitoring and actuating devices. An enabler of this technology is a scalable printing process achieving uniform electrical performances over large area. As opposed to the deposition of highly crystalline films, orientational alignment of polymer chains, albeit commonly achieved by non-scalable/slow bulk alignment schemes, is a more robust approach towards large-area electronics.

Electronic transport regimes through an alkoxythiolated diphenyl-2,2'-bithiophene-based molecular junction diodes: critical assessment of the thermal dependence.

The detailed understanding of electronic transport through a single molecule or an ensemble of self-assembled molecules embedded between two metallic leads is still a matter of controversy. Multiple factors influence the charge transport in the molecular junction, with particular attention to be given to the band states of the electrodes, molecular orbital energies, bias potential and importantly molecule-electrode electronic coupling. Moreover it is not trivial to disentangle molecular contributions from other possible conduction pathways directly coupling the opposite electrodes.

Synthesis, X-ray diffraction characterization, and radiative properties of Er(2)O(3)-ZrO(2) nanocrystals embedded in LAS glass ceramic.

Low thermal expansion Li(2)O-Al(2)O(3)-SiO(2) (LAS) glass ceramic was examined as a host matrix for erbium ions. ZrO(2) was added to the glass since it serves as a nucleating agent and as a good environment for the luminescent ions. The study was carried out on amorphous powders of the Li(2)O-Al(2)O(3)-SiO(2)/ZrO(2)/Er(2)O(3) system prepared by the sol-gel method and successively crystallized at different temperatures.