Stabilization of Copper-Based Biochips with Alumina for Biosensing Application.

Surface plasmon resonance devices typically rely on the use of gold-coated surfaces, but the use of more abundant metals is desirable for the long-term development of plasmonic biochips. As a substitute for gold, thin copper films have been deposited on glass coverslips by thermal evaporation. As expected, these films immersed in a water solution initially exhibit an intense plasmonic resonance comparable to gold.

Sensitivity Enhancement of Hybrid Two-Dimensional Nanomaterials-Based Surface Plasmon Resonance Biosensor.

In this work, we designed structures based on copper nanosubstrate with graphene and two-dimensional transition metal dichalcogenides (TMDC) in order to achieve an ultrasensitive surface plasmon resonance biosensor. This system contains seven components: SF11 triangular prism, BK-7 glass, Chromium (Cr) adhesion layer, thin copper film, layers of one of the types of transition metal dichalcogenides: MoS, MoSe, WS or WSe (defined as MX), graphene, sensing layer with biomolecular analyte. Copper was chosen as a plasmonic material because it has a higher conductivity than gold which is commonly used in plasmonic sensors.

Transition from surface phonon-polariton to surface phonon-plasmon-polariton by thermal injection of free carriers.

Surface phonon-polariton, surface plasmon-polariton, and surface phonon-plasmon-polariton are evanescent electromagnetic waves confined to the surfaces of different classes of materials, which gives each of them particular characteristics suitable for diverse applications. Natural or forced injection of free carriers in a dielectric may change the surface phonon-polariton into a surface phonon-plasmon-polariton. Understanding this effect provides an insight into the fundamental physics of surface electromagnetic waves on dielectrics and offers tools that can be used to develop new technologies.

Multi-Layer Reflectivity Calculation Based Meta-Modeling of the Phase Mapping Function for Highly Reproducible Surface Plasmon Resonance Biosensing.

Phase-sensitive surface plasmon resonance biosensors are known for their high sensitivity. One of the technology bottle-necks of such sensors is that the phase sensorgram, when measured at fixed angle set-up, can lead to low reproducibility as the signal conveys multiple data. Leveraging the sensitivity, while securing satisfying reproducibility, is therefore is an underdiscussed key issue.

Optical density of states near planar ENZ materials.

We study the local density of optical states (LDOS) for lossy dielectric substrates whose electric permittivity has a vanishing real part, approaching zero from the positive side of the real axis. A criterion for evaluating the threshold height above (below) which radiative (non-radiative) processes dominate for a dipole emitter is established. We focus on the case of a vertical dipole above the -near-zero (ENZ) substrate and show that, in the lossless case, complete LDOS cancellation originates from radiative modes in its near field.

Surface plasmons in suspended graphene: launching with in-plane gold nanoantenna and propagation properties.

Graphene physics and plasmonics are two fields which, once combined, promise a variety of exciting applications. One of those applications is the integration of active nano-optoelectronic devices in electronic systems, using the fact that plasmons in graphene are tunable, highly confined and weakly damped. A crucial challenge remains before achieving these active devices: finding a platform enabling a high propagation of Graphene Plasmons Polaritons (GPPs).

Co-axis digital holography based on sinusoidal phase modulation using generalized lock-in detection.

Sinusoidal phase modulating (SPM) interferometers are used to precisely measure complex light fields with simple interferometric setups. Recently, a generalized lock-in technique has been proposed for optimizing the signal extraction in phase-modulated interferometers. This article shows its applicability in digital holography as well as digital holographic interferometry.

Direct measurement of the effective infrared dielectric response of a highly doped semiconductor metamaterial.

We have investigated the effective dielectric response of a subwavelength grating made of highly doped semiconductors (HDS) excited in reflection, using numerical simulations and spectroscopic measurement. The studied system can exhibit strong localized surface resonances and has, therefore, a great potential for surface-enhanced infrared absorption (SEIRA) spectroscopy application. It consists of a highly doped InAsSb grating deposited on lattice-matched GaSb.

DNA biosensor combining single-wavelength colorimetry and a digital lock-in amplifier within a smartphone.

Smartphone camera based gold nanoparticle colorimetry (SCB-AuNP colorimetry) has shown good potential for point-of-care applications. However, due to the use of a camera as a photo-detector, there are major limitations to this technique such as a low bit resolution (∼8 bits mainstream) and a low data acquisition rate. These issues have limited the ultimate sensitivity of smartphone based colorimetry as well as the possibility to integrate efficiently a more sensitive approach such as detection based on a lock-in amplifier (LIA).

Wavelength-scale light concentrator made by direct 3D laser writing of polymer metamaterials.

We report on the realization of functional infrared light concentrators based on a thick layer of air-polymer metamaterial with controlled pore size gradients. The design features an optimum gradient index profile leading to light focusing in the Fresnel zone of the structures for two selected operating wavelength domains near 5.6 and 10.

Compact interferometer transducer based on surface plasmon phase resonance.

We propose a new monolithic interferometric configuration and implement a novel method for spectroscopic phase shift detection of surface plasmon resonance (SPR) sensors. The interference pattern is obtained using a nonpolarizing beam splitter cube with two attached right angle prisms in such a way that each interference field undergoes two total internal reflections (TIR) at prisms/air interface and one attenuated total reflection (ATR) through surface plasmon interaction. The evanescent part of the interferogram around the Zero optical path difference (ZOPD) is sampled and detected in the far field, thanks to a bidimensional array of scattering optical near-field probes deposited on the corresponding prism surface.

Generalized lock-in detection for interferometry: application to phase sensitive spectroscopy and near-field nanoscopy.

A generalized lock-in detection method is proposed to extract amplitude and phase from optical interferometers when an arbitrary periodic phase or frequency modulation is used. The actual modulation function is used to create the reference signals providing an optimal extraction of the useful information, notably for sinusoidal phase modulation. This simple and efficient approach has been tested and applied to phase sensitive spectroscopy and near-field optical measurements.

Waveguide-coupled nanowire as an optical antenna.

We study the optical coupling between a gold nanowire and a silver ion-exchanged waveguide, with special emphasis on the nanowire antenna radiation pattern. We measure the radiation patterns of waveguide-coupled gold nanowires with a height of 70 nm and width of 50 or 150 nm in the 450-700 nm spectral range for TE and TM polarizations. We perform a systematic theoretical study on the wavelength, polarization, nanowire size, and material dependences on the properties of the radiation pattern.

Observation of near-field dipolar interactions involved in a metal nanoparticle chain waveguide.

We present near-field measurements of transverse plasmonic wave propagation in a chain of gold elliptical nanocylinders fed by a silicon refractive waveguide at optical telecommunication wavelengths. Eigenmode amplitude and phase imaging by apertureless scanning near-field optical microscopy allows us to measure the local out-of-plane electric field components and to reveal the exact nature of the excited localized surface plasmon resonances. Furthermore, the coupling mechanism between subsequent metal nanoparticles along the chain is experimentally analyzed by spatial Fourier transformation on the complex near-field cartography, giving a direct experimental proof of plasmonic Bloch mode propagation along array of localized surface plasmons.

Photo-chemical study and optical properties of microtips self- written on vertical laser diodes using NIR photo-polymerization.

Near infra-red (NIR) self-guided photo-polymerization is investigated in the context of micro-optics photo-fabrication on VCSELs (Vertical-Cavity Surface Emitting Lasers). We present the optimized process we have developed to allow for a collective fabrication on III-V devices wafers under real-time optical monitoring. The influence of photo-chemical parameters on final micro-elements dimensions is studied for two types of single mode 760 nm VCSELs.

Implementation of PT symmetric devices using plasmonics: principle and applications.

The so-called PT symmetric devices, which feature ε((-x)) = ε((x))* associated with parity-time symmetry, incorporate both gain and loss and can present a singular eigenvalue behaviour around a critical transition point. The scheme, typically based on co-directional coupled waveguides, is here transposed to the case of variable gain on one arm with fixed losses on the other arm. In this configuration, the scheme exploits the full potential of plasmonics by making a beneficial use of their losses to attain a critical regime that makes switching possible with much lowered gain excursions.

Bidimensional near-field sampling spectrometry.

We report on a concept of compact optical Fourier-transform spectrometer based on bidimensional (2D) spatial sampling of a confined interferogram. The spectrometer consists of a nanostructured glass surface on which two light beams interfere in total internal reflection. Subwavelength spatial sampling of the interferogram near field is achieved by introducing a tilt angle between a 2D array of optical nanoantennas and the interferogram pattern.

Real-space observation of spectral degeneracy breaking in a waveguide-coupled disk microresonator.

We report on the real-space observation of resonant frequency splitting in a high-Q waveguide-coupled silicon-on-insulator microdisk resonator. Phase sensitive near-field analysis reveals the stationary nature of the two resonant states, and spectral investigations clearly show their orthogonality. These measurements emphasize the role of the coupling waveguide in this splitting phenomenon.

Efficient directional coupling between silicon and copper plasmonic nanoslot waveguides: toward metal-oxide-silicon nanophotonics.

Coupling plasmonics and silicon photonics is the best way to bridge the size gap between macroscopic optics and nanodevices in general and especially nanoelectronic devices. We report on the realization of key blocks for future plasmonic planar integrated optics, nano-optical couplers, and nanoslot waveguides that are compatible both with the silicon photonics and the CMOS microelectronics. Copper-based devices provide for very efficient optical coupling, unexpectedly low propagation losses and a broadband sub-50 nm optical confinement.

Enhanced light coupling in sub-wavelength single-mode silicon on insulator waveguides.

We report on NIR efficient end-coupling in single-mode silicon on insulator waveguides. Efficient coupling has been achieved using Polymer-Tipped Optical Fibers (PTOF) of adaptable radius of curvature (ROC). When compared with commercial micro lenses, systematic studies as a function of PTOF ROC, lead for subwavelength PTOF to a coupling factor enhancement as high as 2.

Phase sensitive optical near-field mapping using frequency-shifted laser optical feedback interferometry.

The use of laser optical feedback Imaging (LOFI) for scattering-type scanning near-field optical microscopy (sSNOM) is proposed and investigated. We implement this sensitive imaging method by combining a sSNOM with optical heterodyne interferometry and the dynamic properties of a B class laser source which is here used both as source and detector. Compared with previous near field optical heterodyne experiments, this detection scheme provides an optical amplification that is several orders of magnitude higher, while keeping a low noise phase-sensitive detection.

SNOM signal near plasmonic nanostructures: an analogy with fluorescence decays channels.

Scanning Near-field Optical Microscope (SNOM) is based on local excitations of nanostructures deposited on a substrate (illumination mode). Ideally, the local source behaves like a dipolar emitter so that the SNOM signal is strongly similar to the fluorescence decay rates of an excited molecule that would be located at the SNOM tip position. We present here how the SNOM signal near plasmonic nanostructures can be used to analyze radiative and non-radiative contribution to the fluorescence decay rate.

Enlarged atomic force microscopy scanning scope: novel sample-holder device with millimeter range.

We propose a homemade sample-holder unit used for nanopositionning in two dimensions with a millimeter traveling range. For each displacement axis, the system includes a long range traveling stage and a piezoelectric actuator for accurate positioning. Specific electronics is integrated according to metrological considerations, enhancing the repeatability performances.

Surface plasmon interference excited by tightly focused laser beams.

We show that interfering surface plasmon polaritons can be excited with a focused laser beam at normal incidence to a plane metal film. No protrusions or holes are needed in this excitation scheme. Depending on the axial position of the focus, the intensity distribution on the metal surface is either dominated by interferences between counterpropagating plasmons or by a two-lobe pattern characteristic of localized surface plasmon excitation.

Heterodyne detection of guided waves using a scattering-type Scanning Near-Field Optical Microscope.

An inherent problem to the study of waveguides with strong propagation losses by Scattering-type Scanning Near field Optical Microscopy is the coherent optical background field which disrupts strongly the weak detected near-field signal. We present a technique of heterodyne detection allowing us to overcome this difficulty while amplifying the near field signal. As illustrated in the case of a highly confined SOI structure, this technique, besides the amplitude, provides the local phase variation of the guided field.