Toxic layering and compound extremes: Per- and polyfluoroalkyl substances (PFAS) exposure in rural, environmental justice copper mining communities.

Per- and polyfluoroalkyl substances (PFAS) are pervasive environmental pollutants with significant impacts on ecosystems and public health. This study aimed to characterize PFAS concentrations in an environmental justice community impacted by active/legacy copper mining, compounded by wildfires and flash floods. Additionally, the study explored the (re)mobilization of PFAS and co-occurrence with metal(loid)s following these events.

Motivation toward physical activity in patients with chronic musculoskeletal disorders: a meta-analysis of the efficacy of behavioural interventions.

Musculoskeletal disorders (MDs) represent a global health issue, which can lead to disability. Physical activity (PA) reduces pain and increases physical function among patients with MDs. To promote behavioural changes, it seems important to focus on modifiable factors, such as motivation.

Vapor-phase transport of per and polyfluoroalkyl substances: Processes, modeling, and implications.

An increasing number of studies have demonstrated the presence of per and polyfluoroalkyl substances (PFAS) in the vapor phase. It is therefore important to consider the potential for vapor-phase transport of PFAS in soil and the vadose zone and to investigate the processes impacting the retention and transport of volatile PFAS in soil. It is also critically important to evaluate existing models and develop new models as needed for their application to PFAS vapor-phase transport.

PFAS transport under lower water-saturation conditions characterized with instrumented-column systems.

The transport of PFOS and PFOA in well-characterized sand was investigated for relatively low water saturations. An instrumented column was used for some experiments to provide real-time in-situ monitoring of water saturation and matric potential. The results showed that water saturations and matric potentials varied minimally during the experiments.

High-Resolution Depth-Discrete Analysis of PFAS Distribution and Leaching for a Vadose-Zone Source at an AFFF-Impacted Site.

The long-term leaching of polyfluoroalkyl substances (PFAS) within the vadose zone of an AFFF application site for which the depth to groundwater is approximately 100 m was investigated by characterizing the vertical distribution of PFAS in a high spatial resolution. The great majority (99%) of PFAS mass resides in the upper 3 m of the vadose zone. The depths to which each PFAS migrated, quantified by moment analysis, is an inverse function of molar volume, demonstrating chromatographic separation.

Rethinking pump-and-treat remediation as maximizing contaminated groundwater.

For over half a century, the United States has developed water quality regulations (e.g., Safe Drinking Water Act), which has been accompanied by innumerable advances in contaminant transport and fate, site characterization, and remediation.

An integrated analytical modeling framework for determining site-specific soil screening levels for PFAS.

Soils at many contaminated sites have accumulated a significant amount of per- and polyfluoroalkyl substances (PFAS) and may require remediation to mitigate leaching to groundwater. USEPA's current approaches for determining soil screening levels (SSLs) were developed for non-PFAS contaminants. Because many PFAS are interfacially-active with unique leaching behaviors in soils, the current non-PFAS-specific soil screening models may not be applicable.

Revising the EPA Dilution-Attenuation Soil Screening Model for PFAS.

Per and polyfluoroalkyl substances (PFAS) have been shown to be ubiquitous in the environment, and one issue of critical concern is the leaching of PFAS from soil to groundwater. The risk posed by contaminants present in soil is often assessed in terms of the anticipated impact to groundwater through the determination of soil screening levels (SSLs). The U.

The influence of NAPL distribution on the transport of PFOS in Co-contaminated media.

The objective of this research was to examine the influence of nonuniform NAPL distribution and hydraulic-conductivity heterogeneity on the retention and transport of PFAS. Two-dimensional flow cell experiments were conducted to investigate the impact of NAPL configuration on PFOS retention. Two simplified NAPL configurations were used, one with decane present as residual and the other with greater-than-residual (pool) NAPL saturation.

QSPR-based prediction of air-water interfacial adsorption coefficients for nonionic PFAS with large headgroups.

Air-water interfacial adsorption has been demonstrated to be an important process affecting the retention and distribution of PFAS in soil, surface waters, and the atmosphere, as well as being central to certain remediation methods. Measured or estimated air-water interfacial adsorption coefficients are needed for quantifying and modeling the interfacial adsorption of PFAS. A single-descriptor QSPR model developed in prior work for predicting air-water interfacial adsorption coefficients of PFAS was demonstrated to successfully represent more than 60 different PFAS, comprising all headgroup types and a wide variety of tail structures.

Potential impact of bacteria on the transport of PFAS in porous media.

The transport and fate of per- and poly-fluoroalkyl substances (PFAS) in soil and groundwater is a topic of critical concern. A number of factors and processes may influence the transport and fate of PFAS in porous media. One factor that has received minimal attention to date is the impact of bacteria on the retention and transport of PFAS, which is the focus of this current study.

Predicting Interfacial Tension and Adsorption at Fluid-Fluid Interfaces for Mixtures of PFAS and/or Hydrocarbon Surfactants.

Many per- and polyfluoroalkyl substances (PFAS) are surface-active and adsorb at fluid-fluid interfaces. The interfacial adsorption controls PFAS transport in multiple environmental systems, including leaching through soils, accumulation in aerosols, and treatment methods such as foam fractionation. Most PFAS contamination sites comprise mixtures of PFAS as well as hydrocarbon surfactants, which complicates their adsorption behaviors.

Determining air-water interfacial areas for the retention and transport of PFAS and other interfacially active solutes in unsaturated porous media.

The objective of this work was to determine the methods that produce the most representative measurements and estimations of air-water interfacial area specifically for the retention and transport of PFAS and other interfacially active solutes in unsaturated porous media. Published data sets of air-water interfacial areas obtained with multiple measurement and prediction methods were compared for paired sets of porous media comprising similar median grain diameters, but one with solid-surface roughness (sand) and one without roughness (glass beads). All interfacial areas produced with the multiple diverse methods were coincident for the glass beads, providing validation of the aqueous interfacial tracer-test methods.

Human Health and Ecological Risks Associated with Total and Bioaccessible Concentrations of Cadmium and Lead in Urban Park Soils.

This study investigated the total and bioaccessible concentrations of cadmium (Cd) and lead (Pb) in urban soils and their associated human health and ecological risk. Total and bioaccessible metal concentrations were found within the safe limits except for Cd, surpassing the State Environmental Protection Administration (SEPA) China limit in 9.5% of parks.

Is PFAS from land applied municipal biosolids a significant source of human exposure via groundwater?

Per and polyfluoroakyl substances (PFAS) are emerging contaminants of critical concern commonly found in the bloodstream of most humans in the U.S. They are present in both Class A and B municipal biosolids.

PFOS Mass Flux Reduction/Mass Removal: Impacts of a Lower-Permeability Sand Lens within Otherwise Homogeneous Systems.

Perfluorooctane sulfonic acid (PFOS) is one of the most common per- and polyfluoroalkyl substances (PFAS) and is a significant risk driver for these emerging contaminants of concern. A series of two-dimensional flow cell experiments was conducted to investigate the impact of flow field heterogeneity on the transport, attenuation, and mass removal of PFOS. A simplified model heterogeneous system was employed consisting of a lower-permeability fine sand lens placed within a higher-permeability coarse sand matrix.

General Backward Model to Identify the Source for Contaminants Undergoing Non-Fickian Diffusion in Water.

Pollutant source identification (PSI) has been conducted for four decades for tracking Fickian diffusive pollutants, while PSI for non-Fickian diffusion, well-documented in aquifers and rivers, requires novel, predictive models. To enable PSI for non-Fickian diffusive pollutants, this study derived a general backward model using the fractional-adjoint approach in sensitivity analysis for dissolved contaminants with transport governed by the spatiotemporal fractional advection-dispersion equation (fADE). The backward fADE contains a self-adjoint time-fractional term for subdiffusion and direction-dependent, non-self-adjoint space-fractional terms for superdiffusion.

Sucralose as an oxidative-attenuation tracer for characterizing the application of chemical oxidation for the treatment of 1,4-dioxane.

chemical oxidation (ISCO) has become a widely used soil and groundwater remediation method. Oxidative-attenuation tracers can be used to provide real-time, explicit delineation of contaminant mass-transfer and transformation behavior during an ISCO remediation project. The objective of this study was to evaluate the potential of employing sucralose, a widely used artificial sweetener, as an oxidative-attenuation tracer to characterize the remediation efficiency of 1,4-dioxane (dioxane) by persulfate-based ISCO.

Global distributions, source-type dependencies, and concentration ranges of per- and polyfluoroalkyl substances in groundwater.

A meta-analysis was conducted of published literature reporting concentrations of per- and polyfluoroalkyl substances (PFAS) in groundwater for sites distributed in 20 countries across the globe. Data for >35 PFAS were aggregated from 96 reports published from 1999 to 2021. The final data set comprises approximately 21,000 data points after removal of time-series and duplicate samples as well as non-detects.

PFAS concentrations in soil versus soil porewater: Mass distributions and the impact of adsorption at air-water interfaces.

Determining the risk posed by PFAS leaching from soil to groundwater requires quantification of the magnitude and temporal/spatial variability of PFAS mass discharge from the vadose zone, which is governed in part by the concentrations of PFAS in soil porewater. Porewater concentrations are impacted and mediated by the properties of the PFAS and soil, multiple transport and fate processes, and site conditions. The objective of this research was to delineate the relationship between soil porewater concentrations and soil concentrations, based on a comprehensive model of PFAS mass distribution within a soil sample volume.

Air-water interfacial adsorption of C4-C10 perfluorocarboxylic acids during transport in unsaturated porous media.

The impact of chain length on air-water interfacial adsorption of perfluorocarboxylic acids (PFCAs) during transport in unsaturated quartz sand was investigated. Short-chain (C4-C7: PFBA, PFPeA, PFHxA, PFHpA) and long chain (C8-C10: PFOA, PFNA, PFDA) PFCAs were selected as a representative homologous series. Surface tensions were measured to characterize surface activities of the selected PFCAs.

Air-water interfacial areas relevant for transport of per and poly-fluoroalkyl substances.

Per and polyfluoroalkyl substances (PFAS) present in the soil pose a long-term threat to groundwater. Robust characterization and modeling of PFAS retention and transport in unsaturated systems requires an accurate determination of the magnitude of air-water interfacial area (AWIA). Multiple methods are available for measuring or estimating air-water interfacial area, including x-ray microtomography (XMT), various aqueous and gas-phase interfacial tracer-test (ITT) methods, and thermodynamic-based estimation methods.

The impact of multiple-component PFAS solutions on fluid-fluid interfacial adsorption and transport of PFOS in unsaturated porous media.

The objective of this research was to investigate the impact of multiple-component PFAS solutions on the retention of PFOS during transport in unsaturated porous media. Surface tensions were measured to characterize the impact of co-PFAS on the surface activity of PFOS. Miscible-displacement experiments were conducted to examine the air-water interfacial adsorption of PFOS during transport in single and multi-PFAS systems.

The Co-Transport of PFAS and Cr(VI) in porous media.

PFAS and Cr are present at some sites as co-contaminants. The objective of this research was to investigate the co-transport behavior of per- and polyfluoroalkyl substances (PFAS) and hexavalent chromium (Cr(VI)) in porous media. Miscible-displacement experiments were conducted using two soils and an aquifer sediment with different geochemical properties.

Impact of a Hydrocarbon Surfactant on the Retention and Transport of Perfluorooctanoic Acid in Saturated and Unsaturated Porous Media.

The transport and retention behavior of perfluorooctanoic acid (PFOA) in the presence of a hydrocarbon surfactant under saturated and unsaturated conditions was investigated. Miscible-displacement transport experiments were conducted at different PFOA and sodium dodecyl sulfate (SDS) input ratios to determine the impact of SDS on PFOA adsorption at solid-water and air-water interfaces. A numerical flow and transport model was employed to simulate the experiments.