2-[(4-Chloro-phen-yl)imino]-1,2-di-phenyl-ethanone.

The title Schiff base, CHClNO, obtained from the reaction of 4-chloro aniline with benzil, has an approximate T shape. The dihedral angle between the phenyl rings of the benzil unit is 74.14 (15)°.

Synthesis and crystal structure of 2-(1,3-dithietan-2-yl-idene)cyclo-hexane-1,3-dione.

The title compound, CHOS, contains a cyclo-hexane-1,3-dione ring, which has a twist-boat conformation. The CS ring is close to planar (r.m.

2,6-Di-bromo-4-methyl-aniline.

In the title compound, CHBrN, the C-C-C bond angles of the benzene ring are notably distorted and two short intamolecular N-H⋯Br contacts occur. In the crystal, the mol-ecules are linked by N-H⋯N hydrogen bonds to generate (2) chains propagating in the [100] direction.

Erratum: Crystal structure and Hirshfeld surface analysis of ()-4-(4-hy-droxy-benzyl-idene)-3-methyl-isoxazol-5(4)-one. Corrigendum.

[This corrects the article DOI: 10.1107/S2056989018007867.].

Crystal structure and Hirshfeld surface analysis of 2,6-di-iodo-4-nitro-toluene and 2,4,6-tri-bromo-toluene.

The title compounds, 2,6-di-iodo-4-nitro-toluene (DINT, CHINO) and 2,4,6-tri-bromo-toluene (TBT, CHBr,), are tris-ubstituted toluene mol-ecules. Both mol-ecules are planar, only the H atoms of the methyl group, and the nitro group in DINT, deviate significantly from the plane of the benzene ring. In the crystals of both compounds, mol-ecules stack in columns up the shortest crystallographic axis, .

Crystal structure, characterization and Hirshfeld analysis of bis-{()-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-olato}copper(II) dimethyl sulfoxide monosolvate.

In the title compound, [Cu(CHBrNO)]·CHOS, the Cu atom is tetra-coordinated in a square-planar coordination, being surrounded by two N atoms and two O atoms from two ,-bidentate ()-1-[(2,4,6-tri-bromo-phen-yl)diazen-yl]naphthalen-2-olate ligands. The two N atoms and two O atoms around the metal center are to each other, with an O-Cu-O bond angle of 177.90 (16)° and a N-Cu-N bond angle of 177.

Crystal structure and Hirshfeld surface analysis of ()-4-(4-hy-droxy-benzyl-idene)-3-methyl-isoxazol-5(4)-one.

The title compound, CHNO, contains an isoxazole and a hy-droxy-benzyl-idene ring, which are inclined to each another by 3.18 (8)°. There is an intra-molecular C-H⋯O contact forming an (7) ring.

Crystal structure of 1,3,5-trimethyl-2,4-di-nitro-benzene.

In the title compound, C9H10N2O4, the planes of the nitro groups subtend dihedral angles of 55.04 (15) and 63.23 (15)° with that of the aromatic ring.

Iodo-durene.

1-iodo-2,3,5,6-tetra-methyl-benzene), C10H13I, crystallizes in the chiral space group P212121. The I atom is displaced by 0.1003 (5) Å from the mean plane of the ten C atoms [maximum deviation = 0.