Surfactant adsorption at solid-liquid interfaces is critical for a number of applications of vast industrial interest and can also be used to seed surface-modification processes. Many of the surfaces of interest are nanostructured, as they might present surface roughness at the molecular scale, chemical heterogeneity, as well as a combination of both surface roughness and chemical heterogeneity. These effects provide lateral confinement on the surfactant aggregates.
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