Multi-stage and multi-colour liquid crystal reflections using a chiral triptycene photoswitchable dopant.

The photomodulation of the helical pitch of cholesteric liquid crystals results in dynamic and coloured canvases that can potentially be used in applications ranging from energy-efficient displays to colour filters, anti-counterfeiting tags and liquid crystal (LC) lasers. Here we report on the analysis of a series of photoswitchable chiral dopants that combine the large geometrical change and bistability of hydrazone switches with the efficient helical pitch induction of the chiral motif, triptycene. We elucidate the effects that conformational flexibility, dispersion forces and π-π interactions have on the chirality transfer ability of the dopant.

Tuning the Properties of Hydrazone/Isosorbide-Based Switchable Chiral Dopants.

The long-range supramolecular interactions in liquid crystals (LCs) can be used to amplify and subsequently propagate microscopic structural changes into macroscopic events. Here, we report on a systematic structure-property analysis using 16 chiral photoswitchable dopants composed of bistable hydrazones and chiral isosorbide moieties. Our findings showcase the relationship between the dopant's structure and its helical twisting power (β), and hence, the photophysical properties of the host LC.